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Zhao, Ming
Publications (10 of 12) Show all publications
Adnane, B., Karlsson, F., Zhao, M., Hansson, G., Holtz, P.-O. & Ni, W.-X. (2009). Origin of photoresponse at 8-14 μm in stacks of self-assembled SiGe/Si quantum dots. Physical Review B. Condensed Matter and Materials Physics
Open this publication in new window or tab >>Origin of photoresponse at 8-14 μm in stacks of self-assembled SiGe/Si quantum dots
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2009 (English)In: Physical Review B. Condensed Matter and Materials Physics, ISSN 1098-0121, E-ISSN 1550-235XArticle in journal (Other academic) Submitted
Abstract [en]

A normal incidence photodetector operating at 8-14 μm is demonstrated using p-type δ-doped SiGe dot multilayer structures grown by molecular beam epitaxy on Si(001) substrates. Based on the experimental results of photoluminescence and photoluminescence excitation spectroscopies together with numerical analysis, the origin of the measured photocurrent was attributed to intersubband optical transitions between the heavy hole and light hole states of the valence band of the self-assembled SiGe dots and subsequent lateral transport of photo-excited carriers in the conduction channels formed by Ge wetting layers.

National Category
Natural Sciences
Identifiers
urn:nbn:se:liu:diva-53203 (URN)
Available from: 2010-01-19 Created: 2010-01-19 Last updated: 2017-12-12
Zhao, M., Hansson, G. & Ni , W.-X. (2009). Strain relaxation of thin Si0.6Ge0.4 grown with low-temperature buffers by molecular beam epitaxy. JOURNAL OF APPLIED PHYSICS, 105(6), 063502-
Open this publication in new window or tab >>Strain relaxation of thin Si0.6Ge0.4 grown with low-temperature buffers by molecular beam epitaxy
2009 (English)In: JOURNAL OF APPLIED PHYSICS, ISSN 0021-8979 , Vol. 105, no 6, p. 063502-Article in journal (Refereed) Published
Abstract [en]

A double-low-temperature-buffer variable-temperature growth scheme was studied for fabrication of strain-relaxed thin Si0.6Ge0.4 layer on Si(001) by using molecular beam epitaxy (MBE), with particular focuses on the influence of growth temperature of individual low-temperature-buffer layers on the relaxation process and final structural qualities. The low-temperature buffers consisted of a 40 nm Si layer grown at an optimized temperature of similar to 400 degrees C, followed by a 20 nm Si0.6Ge0.4 layer grown at temperatures ranging from 50 to 550 degrees C. A significant relaxation increase together with a surface roughness decrease both by a factor of similar to 2, accompanied with the cross-hatch/cross-hatch-free surface morphology transition, took place for the sample containing a low-temperature Si0.6Ge0.4 layer that was grown at similar to 200 degrees C. This dramatic change was explained by the association with a certain onset stage of the ordered/disordered growth transition during the low-temperature MBE, where the high density of misfit dislocation segments generated near surface cusps largely facilitated the strain relaxation of the top Si0.6Ge0.4 layer.

Keywords
buffer layers, dislocations, Ge-Si alloys, molecular beam epitaxial growth, order-disorder transformations, semiconductor growth, semiconductor materials, semiconductor thin films, surface morphology, surface roughness
National Category
Natural Sciences
Identifiers
urn:nbn:se:liu:diva-17893 (URN)10.1063/1.3091266 (DOI)
Note
Original Publication: Ming Zhao, Göran Hansson and Wei-Xin Ni, Strain relaxation of thin Si0.6Ge0.4 grown with low-temperature buffers by molecular beam epitaxy, 2009, JOURNAL OF APPLIED PHYSICS, (105), 6, 063502. http://dx.doi.org/10.1063/1.3091266 Copyright: American Institute of Physics http://www.aip.org/ Available from: 2009-05-05 Created: 2009-04-24 Last updated: 2009-05-05Bibliographically approved
Zhao, M. (2008). Growth and Characterization of Strain-engineered Si/SiGe Heterostructures Prepared by Molecular Beam Epitaxy. (Doctoral dissertation). Linköping: Linköping University Electronic Press
Open this publication in new window or tab >>Growth and Characterization of Strain-engineered Si/SiGe Heterostructures Prepared by Molecular Beam Epitaxy
2008 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

The strain introduced by lattice mismatch is a built-in characteristic in Si/SiGe heterostructures, which has significant influences on various material properties. Proper design and precise control of strain within Si/SiGe heterostructures, i.e. the so-called “strain engineering”, have become a very important way not only for substantial performance enhancement of conventional microelectronic devices, but also to allow novel device concepts to be integrated with Si chips for new functions, e.g. Si-based optoelectronics. This thesis thus describes studies on two subjects of such strain-engineered Si/SiGe heterostructures grown by molecular beam epitaxy (MBE). The first one focuses on the growth and characterizations of delicately strain-symmetrized Si/SiGe multi-quantum-well/superlattice structures on fully relaxed SiGe virtual substrates for light emission in the THz frequency range. The second one investigates the strain relaxation mechanism of thin SiGe layers during MBE growth and post-growth processes in non-conventional conditions.

Two types of THz emitters, based on different quantum cascade (QC) intersubband transition schemes, were studied. The QC emitters using the diagonal transition between two adjacent wells were grown with Si/Si0.7Ge0.3 superlattices up to 100 periods. It was shown that nearly perfect strain symmetry in the superlattice with a high material quality was obtained. The layer parameters were precisely controlled with deviations of ≤ 2 Å in layer thickness and ≤ 1.5 at. % in Ge composition from the designed values. The fabricated emitter devices exhibited a dominating emission peak at ~13 meV (~3 THz), which was consistent with the design. An attempt to produce the first QC THz emitter based on the bound-to-continuum transition was made. The structures with a complicated design of 20 periods of active units were extremely challenging for the growth. Each unit contained 16 Si/Si0.724Ge0.276 superlattice layers, in which the thinnest one was only 8 Å. The growth parameters were carefully studied, and several samples with different boron δ-doping concentrations were grown at optimized conditions. Extensive material characterizations revealed a high crystalline quality of the grown structures with an excellent growth control, while the heavy δ-doping may introduce layer undulations as a result of the non-uniformity in the strain field. Moreover, carrier lifetime dynamics, which is crucial for the THz QC structure design, was also investigated. Strain-symmetrized Si/SiGe multi-quantum-well structures, designed for probing the carrier lifetime of intersubband transitions inside a well between heavy hole 1 (HH1) and light hole 1 (LH1) states with transition energies below the optical phonon energy, were grown on SiGe virtual substrates. The lifetime of the LH1 excited state was determined directly with pump-probe spectroscopy. The measurements indicated an increase of lifetime by a factor of ~2 due to the increasingly unconfined LH1 state, which agreed very well with the theory. It also showed a very long lifetime of several hundred picoseconds for the holes excited out of the well to transit back to the well through a diagonal process.

Strained SiGe grown on Si (110) substrates has promising potentials for high-speed microelectronics devices due to the enhanced carrier mobility. Strain relaxation of SiGe/Si(110) subjected to different annealing treatments was studied by X-ray reciprocal space mapping. The in-plane lattice mismatch was found to be asymmetric with the major strain relaxation observed in the lateral [001] direction. It was concluded that this was associated to the formation and propagation of conventional a/2<110> dislocations oriented along [110]. This was different from the relaxation observed during growth, which was mainly along in-plane [110].

A novel MBE growth process to fabricate thin strain-relaxed Si0.6Ge0.4 virtual substrates involving low-temperature (LT) buffer layers was investigated. At a certain LT-buffer growth temperature, a dramatic increase in the strain relaxation accompanied with a decrease of surface roughness was observed in the top SiGe, together with a cross-hatch/cross-hatch-free transition in the surface morphology. It was explained by the association with a certain onset stage of the ordered/disordered transition during the growth of the LT-SiGe buffer.

Abstract [sv]

Kisel(Si)-baserad mikroelektronik har utvecklats under en femtioårsperiod till att bli basen för vår nuvarande informationsteknologi. Förutom att integrera fler och mindre komponenter på varje kisel-chip så utvecklas metoder att modifiera och förbättra materialegenskaperna för att förbättra prestanda ytterligare. Ett sätt att göra detta är att kombinera kisel med germanium (Ge) bl.a. för att skapa kvantstrukturer av nanometer-storlek. Eftersom Ge-atomerna är större än Si-atomerna kan man skapa en töjning i materialet vilket kan förbättra egenskaperna, ex.vis hur snabbt laddningarna (elektronerna) rör sig i materialet. Genom att variera Gekoncentrationen i tunna skikt kan man skapa skikt som är antingen komprimerade eller expanderade och därmed ger möjlighet att göra strukturer för tillverkning av nya typer av komponenter för mikroelektronik eller optoelektronik. I detta avhandlingsarbete har Si/SiGe nanostrukturer tillverkats med molekylstråle-epitaxi-teknik (molecular beam epitaxy, MBE). Med denna teknik byggs materialet upp på ett substrat, atomlager för atomlager, med mycket god kontroll på sammansättningen av varje skikt. Samtidigt kan töjningen av materialet designas så att inga defekter skapas alternativt många defekter genereras på ett kontrollerat sätt. I denna avhandling beskrivs detaljerade studier av hur töjda i/SiGe-strukturer kan tillverkas och ge nya potentiella tillämpningar ex.vis som källa för infraröd strålning. Studierna av de olika töjda skikten har framför allt gjorts med avancerade röntgendiffraktionsmätningar och transmissionselektronmikroskopi.

Place, publisher, year, edition, pages
Linköping: Linköping University Electronic Press, 2008. p. 69
Series
Linköping Studies in Science and Technology. Dissertations, ISSN 0345-7524 ; 1176
Keywords
Si/SiGe, Strain engineering, Molecular beam epitaxy, THz, Quantum cascade, Strain relaxation
National Category
Materials Engineering
Identifiers
urn:nbn:se:liu:diva-11746 (URN)978-91-7393-911-9 (ISBN)
Public defence
2008-06-02, Planck, Fysikhuset, Campus Valla, Linköpings universitet, Linköping, 10:15 (English)
Opponent
Supervisors
Available from: 2008-05-07 Created: 2008-05-07 Last updated: 2009-05-19Bibliographically approved
Zhao, M., Karim, A., Hansson, G., Ni, W.-X., Townsend, P., Lynch, S. A. & Paul , D. J. (2008). Molecular beam epitaxy growth of Si/SiGe bound-to-continuum quantum cascade structures for THz emission. Thin Solid Films, 517(1), 34-37
Open this publication in new window or tab >>Molecular beam epitaxy growth of Si/SiGe bound-to-continuum quantum cascade structures for THz emission
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2008 (English)In: Thin Solid Films, ISSN 0040-6090, E-ISSN 1879-2731, Vol. 517, no 1, p. 34-37Article in journal (Refereed) Published
Abstract [en]

A Si/SiGe bound-to-continuum quantum cascade design for THz emission was grown using solid-source molecular beam epitaxy on Si0.8Ge0.2 virtual substrates. The growth parameters were carefully studied and several samples with different boron doping concentrations were grown at optimized conditions. Extensive material characterizations revealed a high crystalline quality of the grown structures with an excellent growth control. Layer undulations resulting from a nonuniform strain field, introduced by high doping concentration, were observed. The device characterizations suggested that a modification on the design was needed in order to enhance the THz emission.

Keywords
Molecular beam epitaxy (MBE), Si/SiGe, Quantum cascade, X-ray diffraction, Transmission electron microscopy (TEM)
National Category
Natural Sciences
Identifiers
urn:nbn:se:liu:diva-16177 (URN)10.1016/j.tsf.2008.08.091 (DOI)
Available from: 2009-01-09 Created: 2009-01-09 Last updated: 2017-12-14
Paul, D., Matmon, G., Townsend, P., Zhang, J., Zhao, M. & Ni, W.-X. (2007). A Review Of Progress Towards Terahertz Si/SiGe Quantum Cascade Lasers. Journal of the Institution of Electronics and Telecommunication Engineers, 53(3), 285-292
Open this publication in new window or tab >>A Review Of Progress Towards Terahertz Si/SiGe Quantum Cascade Lasers
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2007 (English)In: Journal of the Institution of Electronics and Telecommunication Engineers, ISSN 0377-2063, E-ISSN 0974-780X, Vol. 53, no 3, p. 285-292Article, review/survey (Refereed) Published
Abstract [en]

[ABST].

Place, publisher, year, edition, pages
Medknow Publications, 2007
National Category
Engineering and Technology
Identifiers
urn:nbn:se:liu:diva-59153 (URN)000207330100009 ()
Available from: 2010-09-10 Created: 2010-09-09 Last updated: 2017-12-12
Rauter, P., Fromherz, T., Vinh, N., Murdin, B., Phillips, J., Pidgeon, C., . . . Bauer, G. (2007). Direct determination of ultrafast intersubband hole relaxation times in voltage biased SiGe quantum wells by a density matrix interpretation of femtosecond resolved photocurrent experiments. New Journal of Physics, 9
Open this publication in new window or tab >>Direct determination of ultrafast intersubband hole relaxation times in voltage biased SiGe quantum wells by a density matrix interpretation of femtosecond resolved photocurrent experiments
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2007 (English)In: New Journal of Physics, ISSN 1367-2630, E-ISSN 1367-2630, Vol. 9Article in journal (Refereed) Published
Abstract [en]

We report the quantitative and direct determination of hole intersubband relaxation times in a voltage biased SiGe heterostructure using density matrix calculations applied to a four-level system in order to interpret photocurrent (PC) pump-pump experiments. One consistent set of parameters allows the simulation of two kinds of experiments, namely pump-pump photocurrent experiments at a free electron laser (wavelength 7.9 mu m) and the laser-power dependence of the PC signal. This strongly confirms the high reliability of these parameter values, of which the most interesting in respect to Si based quantum cascade laser development is the extracted heavy-hole relaxation time. The simulations show that this relaxation time directly determines the experimentally observed decay of the pump-pump photocurrent signal as a function of the delay time. For a heavy hole intersubband spacing of 160 meV, a value of 550 fs was obtained. The experimental method was further applied to determine the LH1-HH1 relaxation time of a second sample with a transition energy below the optical phonon energy. The observed relaxation time of 16 ps is consistent with the value found for the same structure by transmission pump-probe experiments.

Place, publisher, year, edition, pages
Institute of Physics (IoP) and Deutsche Physikalische Gesellschaft, 2007
National Category
Engineering and Technology
Identifiers
urn:nbn:se:liu:diva-59152 (URN)10.1088/1367-2630/9/5/128 (DOI)000251912800001 ()
Available from: 2010-09-10 Created: 2010-09-09 Last updated: 2017-12-12
Elfving, A., Zhao, M., Hansson, G. V. & Ni, W.-X. (2006). Asymmetric relaxation of SiGe/Si(110) investigated by high-resolution x-ray diffraction reciprocal space mapping. Applied physics letters, 89, 181901-1--181901-3
Open this publication in new window or tab >>Asymmetric relaxation of SiGe/Si(110) investigated by high-resolution x-ray diffraction reciprocal space mapping
2006 (English)In: Applied physics letters, ISSN 0003-6951, Vol. 89, p. 181901-1--181901-3Article in journal (Refereed) Published
Abstract [en]

Strain relaxation of SiGe/Si(110) has been studied by x-ray reciprocal space mapping. To get information about the in-plane lattice mismatch in different directions, two-dimensional maps around, e.g., (260) and (062) reciprocal lattice points have been obtained from Si0.8Ge0.2/Si(110) samples, which were exposed to different annealing conditions. The in-plane lattice mismatch was found to be asymmetric with the major strain relaxation observed in the lateral [001] direction. This was associated with the formation and propagation of dislocations oriented along [10]. The relaxation of as-grown structures during postannealing is thus different from relaxation during growth, which is mainly along [10].

 

 

Keywords
Ge-Si alloys, silicon, semiconductor materials, elemental semiconductors, X-ray diffraction, annealing, dislocations, stress relaxation
National Category
Natural Sciences
Identifiers
urn:nbn:se:liu:diva-13276 (URN)10.1063/1.2364861 (DOI)
Available from: 2008-05-07 Created: 2008-05-07 Last updated: 2009-05-11
Zhao, M., Ni, W.- . X., Townsend, P., Lynch, S. A., Paul, D. J., Chang, M. N. & Hsu, C. C. (2006). Low-temperature molecular beam epitaxy growth of Si/SiGe THz quantum cascade structures on virtual substrates. Thin Solid Films, 508(1-2), 24-28
Open this publication in new window or tab >>Low-temperature molecular beam epitaxy growth of Si/SiGe THz quantum cascade structures on virtual substrates
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2006 (English)In: Thin Solid Films, ISSN 0040-6090, Vol. 508, no 1-2, p. 24-28Article in journal (Refereed) Published
Abstract [en]

Si/SiGe quantum cascade structures containing superlattice up to 100 periods have been grown on SiGe virtual substrates by using solid-source molecular beam epitaxy at low temperature. The surface morphology and structural properties of the grown samples were characterized using various experimental techniques. It has been concluded that the structures were completely symmetrically strained with high crystalline quality, precise layer parameters, and excellent reproducibility. Electroluminescence was observed with peaked intensity at 3 THz at both 4 and 40 K, which agrees very well with expected interwell intersubband transition according to the design.

Keywords
Molecular beam epitaxy (MBE); Si/SiGe; Quantum cascade; X-ray diffraction
National Category
Engineering and Technology
Identifiers
urn:nbn:se:liu:diva-13273 (URN)10.1016/j.tsf.2005.07.355 (DOI)
Available from: 2008-05-07 Created: 2008-05-07
Zhao, M., Karim, A., Ni, W.-X., Pidgeon, C. R., Phillips, P. J., Carder, D., . . . Paul, D. J. (2006). Strain-symmetrized Si/SiGe multi-quantum well structures grown by molecular beam epitaxy for intersubband engineering. Journal of luminescence, 121(2), 403-408
Open this publication in new window or tab >>Strain-symmetrized Si/SiGe multi-quantum well structures grown by molecular beam epitaxy for intersubband engineering
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2006 (English)In: Journal of luminescence, ISSN 0022-2313, Vol. 121, no 2, p. 403-408Article in journal (Refereed) Published
Abstract [en]

Three strain-symmetrized Si/SiGe multi-quantum well structures, designed for probing the carrier lifetime of intrawell intersubband transitions between heavy hole 1 (HH1) and light hole 1 (LH1) states with transition energies below the optical phonon energy, were grown by molecular beam epitaxy at low temperature on fully relaxed SiGe virtual substrates. The grown structures were characterized by using various experimental techniques, showing a high crystalline quality and very precise growth control. The lifetime of the LH1 excited state was determined directly with pump-probe spectroscopy. The measurements indicated an increase of the lifetime by a factor of 2 due to the increasingly unconfined LH1 state, which agreed very well with the design. It also showed a very long lifetime of several hundred picoseconds for the holes excited out of the well to transit back to the well through a diagonal process.

Keywords
Molecular beam epitaxy (MBE); Si/SiGe; Pump-probe spectroscopy; Intersubband transition; Lifetime
National Category
Engineering and Technology
Identifiers
urn:nbn:se:liu:diva-13274 (URN)10.1016/j.jlumin.2006.08.080 (DOI)
Available from: 2008-05-07 Created: 2008-05-07
Lynch, S., Paul, D., Townsend, P., Matmon, G., Suet, Z., Kelsall, R., . . . Ni, W.-X. (2006). Toward silicon-based lasers for terahertz sources. IEEE Journal of Selected Topics in Quantum Electronics, 12(6), 1570-1577
Open this publication in new window or tab >>Toward silicon-based lasers for terahertz sources
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2006 (English)In: IEEE Journal of Selected Topics in Quantum Electronics, ISSN 1077-260X, E-ISSN 1558-4542, Vol. 12, no 6, p. 1570-1577Article in journal (Refereed) Published
Abstract [en]

Producing an electrically pumped silicon-based laser at terahertz frequencies is gaining increased attention these days. This paper reviews the recent advances in the search for a silicon-based terahertz laser. Topics covered include resonant tunneling in p-type Si/SiGe, terahertz intersubband electroluminescence from quantum cascade structures, intersubband lifetime measurements in Si/SiGe quantum wells, enhanced optical guiding using buried suicide layers, and the potential for exploiting common impurity dopants in silicon such as boron and phosphorus to realize a terahertz laser. © 2006 IEEE.

Keywords
Boron, Far infrared, Germanium, Impurity, Lifetime, Phosphorus, Pump-probe, Quantum cascade laser, Resonant tunneling diode (RTD), Silicon, Suicide, Terahertz, Waveguide
National Category
Engineering and Technology
Identifiers
urn:nbn:se:liu:diva-50083 (URN)10.1109/JSTQE.2006.884069 (DOI)
Available from: 2009-10-11 Created: 2009-10-11 Last updated: 2017-12-12
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