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Sangiovanni, Davide GiuseppeORCID iD iconorcid.org/0000-0002-1379-6656
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Publications (10 of 35) Show all publications
Shi, Y., Kashiwaya, S., Lu, J., Dahlqvist, M., Sangiovanni, D. G., Rogoz, V., . . . Hultman, L. (2025). Synthesis of Ti4Au3C3 and its derivative trilayer goldene through chemical exfoliation. Science Advances, 11(13)
Open this publication in new window or tab >>Synthesis of Ti4Au3C3 and its derivative trilayer goldene through chemical exfoliation
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2025 (English)In: Science Advances, E-ISSN 2375-2548, Vol. 11, no 13Article in journal (Refereed) Published
Abstract [en]

Achieving large two-dimensional (2D) sheets of any metal is challenging due to their tendency to coalescence or cluster into 3D shapes. Recently, single-atom-thick gold sheets, termed goldene, was reported. Here, we ask if goldene can be extended to include multiple layers. The answer is yes, and trilayer goldene is the magic number, for reasons of electronegativity. Experiments are made to synthesize the atomically laminated phase Ti4Au3C3 through substitutional intercalation of Si layers in Ti4SiC3 for Au. Density functional theory calculations suggest that it is energetically favorable to insert three layers of Au into Ti4SiC3, compared to inserting a monolayer, a bilayer, or more than three layers. Isolated trilayer goldene sheets, ~100 nanometers wide and 6.7 angstroms thick, were obtained by chemically etching the Ti4C3 layers from Ti4Au3C3 templates. Furthermore, trilayer goldene is found in both hcp and fcc forms, where the hcp is ~50 milli–electron volts per atom more stable at room temperature from ab initio molecular dynamic simulations.

Place, publisher, year, edition, pages
American Association for the Advancement of Science (AAAS), 2025
National Category
Condensed Matter Physics
Identifiers
urn:nbn:se:liu:diva-212681 (URN)10.1126/sciadv.adt7999 (DOI)001455518300003 ()40153494 (PubMedID)2-s2.0-105001593083 (Scopus ID)
Note

Funding Agencies|Swedish Research Council [2023- 04107, 2021- 04426, VR- 2018- 05973, 2022- 06725, 2021- 00171]; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoping University [SFO- Mat-LiU 2009 00971]; Aforsk Foundation [23- 591, 22- 4]; MIRAI2.0 Joint seed funding; Scandinavia- Japan Sasakawa Foundation; Wallenberg Launchpad (WALP); Olle Engkvist foundation [222- 0053]; Carl Tryggers Stiftelse [CTS 20:150]; Swedish Energy Agency [43606-1]; Carl Tryggers Foundation [CTS23:2746, CTS 20:272, CTS16:303, CTS14:310]; Goran Gustafsson Foundation for Research in Natural Sciences and Medicine; Wallenberg Scholar Grant [2019.0433]; Wallenberg Initiative Materials Science for Sustainability (WISE) - Knut and Alice Wallenberg Foundation

Available from: 2025-03-31 Created: 2025-03-31 Last updated: 2025-04-17
Kashiwaya, S., Shi, Y., Lu, J., Sangiovanni, D. G., Greczynski, G., Magnuson, M., . . . Hultman, L. (2024). Synthesis of goldene comprising single-atom layer gold. Nature Synthesis, 3(6), 744-751
Open this publication in new window or tab >>Synthesis of goldene comprising single-atom layer gold
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2024 (English)In: Nature Synthesis, E-ISSN 2731-0582, Vol. 3, no 6, p. 744-751Article in journal (Refereed) Published
Abstract [en]

The synthesis of monolayer gold has so far been limited to free-standingseveral-atoms-thick layers, or monolayers confned on or inside templates.Here we report the exfoliation of single-atom-thick gold achieved throughwet-chemically etching away Ti3C2 from nanolaminated Ti3AuC2, initiallyformed by substituting Si in Ti3SiC2 with Au. Ti3SiC2 is a renown MAX phase,where M is a transition metal, A is a group A element, and X is C or N. Ourdeveloped synthetic route is by a facile, scalable and hydrofuoric acid-freemethod. The two-dimensional layers are termed goldene. Goldene layerswith roughly 9% lattice contraction compared to bulk gold are observedby electron microscopy. While ab initio molecular dynamics simulationsshow that two-dimensional goldene is inherently stable, experiments showsome curling and agglomeration, which can be mitigated by surfactants.X-ray photoelectron spectroscopy reveals an Au 4f binding energy increaseof 0.88 eV. Prospects for preparing goldene from other non-van der WaalsAu-intercalated phases, including developing etching schemes,are presented.

Place, publisher, year, edition, pages
Nature Publishing Group, 2024
National Category
Condensed Matter Physics
Identifiers
urn:nbn:se:liu:diva-202582 (URN)10.1038/s44160-024-00518-4 (DOI)001203366300001 ()2-s2.0-85190684420 (Scopus ID)
Note

Funding agencies: the Swedish Research Council project grant nos. 2017-03909 (L.H.), 2023-04107 (L.H.) and 2021-04426 (D.G.S.), Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linköping University grant no. SFO-Mat-LiU 2009 00971, Wallenberg Scholar Program grant no. KAW 2019.0290 (L.H.), the Swedish Research Council through grant agreement nos. VR-2018-05973 and 2022-06725, MIRAI2.0, Åforsk Foundation grant no. 22-4, the Olle Engkvist foundation grant no. 222-0053, Carl Tryggers Stiftelse contract no. CTS 20:150, Swedish Energy Agency (grant no. 43606-1), Carl Tryggers Foundation (grant nos. CTS23:2746, CTS 20:272, CTS16:303, CTS14:310)and Göran Gustafsson Foundation for Research in Natural Sciences and Medicines.

Available from: 2024-04-17 Created: 2024-04-17 Last updated: 2025-02-06Bibliographically approved
Pshyk, O. V., Li, X., Petrov, I., Sangiovanni, D. G., Palisaitis, J., Hultman, L. & Greczynski, G. (2023). Discovery of Guinier-Preston zone hardening in refractory nitride ceramics. Acta Materialia, 255, Article ID 119105.
Open this publication in new window or tab >>Discovery of Guinier-Preston zone hardening in refractory nitride ceramics
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2023 (English)In: Acta Materialia, ISSN 1359-6454, E-ISSN 1873-2453, Vol. 255, article id 119105Article in journal (Refereed) Published
Abstract [en]

Traditional age hardening mechanisms in refractory ceramics consist of precipitation of fine particles. These processes are vital for widespread wear-resistant coating applications. Here, we report novel Guinier-Preston zone hardening, previously only known to operate in soft light-metal alloys, taking place in refractory ceramics like multicomponent nitrides. The added superhardening, discovered in thin films of Ti-Al-W-N upon high temperature annealing, comes from the formation of atomic-plane-thick W disks populating {111} planes of the cubic matrix, as observed by atomically resolved high resolution scanning transmission electron microscopy and corroborated by ab initio calculations and molecular dynamics simulations. Guinier-Preston zone hardening concurrent with spinodal decomposition is projected to exist in a range of other ceramic solid solutions and thus provides a new approach for the development of advanced materials with outstanding mechanical properties and higher operational temperature range for the future demanding applications.

Place, publisher, year, edition, pages
Elsevier, 2023
Keywords
Guinier-Preston zone, TiAlN, Ceramics, Age hardening, Spinodal decomposition
National Category
Condensed Matter Physics
Identifiers
urn:nbn:se:liu:diva-196410 (URN)10.1016/j.actamat.2023.119105 (DOI)001025995100001 ()
Note

Funding: Swedish Research Council VR [2018-03957, 2021-03652, 2021-04426]; Swedish Energy Agency [51201-1]; Knut and Alice Wallenberg Foundation [KAW2019.0290, CTS 20:150]; Carl Tryggers Stiftelse [21:1272, 2017-00646_9]; Swedish Research Council VR-RFI [VR-2018-0597]; Swedish Foundation for Strategic Research [2021-00171]; Swedish Research Council [RIF21-0026]; Swedish National Infrastructure in Advanced Electron Microscopy [22-4, 2022-03071]; Aforsk Foundation; Competence Center Functional Nanoscale Materials (FunMat-II) VINNOVA;  [KAW2016.0358];  [RIF14-0053]

Available from: 2023-08-01 Created: 2023-08-01 Last updated: 2023-08-31
Salamania, J., Calamba Kwick, K., Sangiovanni, D. G., Tasnadi, F., Abrikosov, I. A., Rogström, L., . . . Odén, M. (2023). High-resolution STEM investigation of the role of dislocations during decomposition of Ti1-xAlxNy. Scripta Materialia, 229, Article ID 115366.
Open this publication in new window or tab >>High-resolution STEM investigation of the role of dislocations during decomposition of Ti1-xAlxNy
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2023 (English)In: Scripta Materialia, ISSN 1359-6462, E-ISSN 1872-8456, Vol. 229, article id 115366Article in journal (Refereed) Published
Abstract [en]

The defect structures forming during high-temperature decomposition of Ti1-xAlxNy films were investigated through high-resolution scanning transmission electron microscopy. After annealing to 950 °C, misfit edge dislocations a/6〈112〉{111} partial dislocations permeate the interface between TiN-rich and AlN-rich domains to accommodate lattice misfits during spinodal decomposition. The stacking fault energy associated with the partial dislocations decreases with increasing Al content, which facilitates the coherent cubic to wurtzite structure transition of AlN-rich domains. The wurtzite AlN-rich structure is recovered when every third cubic {111} plane is shifted by along the [211] direction. After annealing to 1100 °C, a temperature where coarsening dominates the microstructure evolution, we observe intersections of stacking faults, which form sessile locks at the interface of the TiN- and AlN-rich domains. These observed defect structures facilitate the formation of semicoherent interfaces and contribute to hardening in Ti1-xAlxNy.

Place, publisher, year, edition, pages
Elsevier, 2023
National Category
Other Materials Engineering
Identifiers
urn:nbn:se:liu:diva-191923 (URN)10.1016/j.scriptamat.2023.115366 (DOI)000946547000001 ()
Funder
Vinnova, 2016–05156
Note

Funding: Swedish Research Council (VR) [2017-03813, 2017-06701, 2021-04426, 2021-00357]; ViNNOVA [2016-05156]; Swedish government strategic research area grant AFM - SFO MatLiU [2009-00971]; Knut and Alice Wallenberg Foundation [KAW-2018.0194]; Swedish Research Council [VR-2015-04630]

Available from: 2023-02-23 Created: 2023-02-23 Last updated: 2023-04-11Bibliographically approved
Chen, Z., Huang, Y., Koutná, N., Gao, Z., Sangiovanni, D. G., Fellner, S., . . . Zhang, Z. (2023). Large mechanical properties enhancement in ceramics through vacancy-mediated unit cell disturbance. Nature Communications, 14(1), Article ID 8387.
Open this publication in new window or tab >>Large mechanical properties enhancement in ceramics through vacancy-mediated unit cell disturbance
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2023 (English)In: Nature Communications, E-ISSN 2041-1723, Vol. 14, no 1, article id 8387Article in journal (Refereed) Published
Abstract [en]

Tailoring vacancies is a feasible way to improve the mechanical properties of ceramics. However, high concentrations of vacancies usually compromise the strength (or hardness). We show that a high elasticity and flexural strength could be achieved simultaneously using a nitride superlattice architecture with disordered anion vacancies up to 50%. Enhanced mechanical properties primarily result from a distinctive deformation mechanism in superlattice ceramics, i.e., unit-cell disturbances. Such a disturbance substantially relieves local high-stress concentration, thus enhancing deformability. No dislocation activity involved also rationalizes its high strength. The work renders a unique understanding of the deformation and strengthening/toughening mechanism in nitride ceramics.

Place, publisher, year, edition, pages
Nature Publishing Group, 2023
National Category
Physical Sciences
Identifiers
urn:nbn:se:liu:diva-201116 (URN)10.1038/s41467-023-44060-x (DOI)001130352200011 ()38104109 (PubMedID)2-s2.0-85179936308 (Scopus ID)
Note

Funding: Austrian Science Fund (Fonds zur Frderung der Wissenschaftlichen Forschung) [FWF P 33696]; China Scholarship Council (CSC) [201908440933]; Competence Center Functional Nanoscale Materials (FunMat-II) (Vinnova) [2022-03071]; Swedish Research Council (VR) [Ndegrees VR-2021-04426]; Swedish Research Council [Ndegrees VR-2015-04630]

Available from: 2024-02-22 Created: 2024-02-22 Last updated: 2024-12-05Bibliographically approved
Salamania, J., Sangiovanni, D. G., Kraych, A., Calamba Kwick, K., Schramm, I., Johnson, L., . . . Odén, M. (2022). Elucidating dislocation core structures in titanium nitride through high-resolution imaging and atomistic simulations. Materials & design, 224, Article ID 111327.
Open this publication in new window or tab >>Elucidating dislocation core structures in titanium nitride through high-resolution imaging and atomistic simulations
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2022 (English)In: Materials & design, ISSN 0264-1275, E-ISSN 1873-4197, Vol. 224, article id 111327Article in journal (Refereed) Published
Abstract [en]

Although titanium nitride (TiN) is among the most extensively studied and thoroughly characterizedthin-film ceramic materials, detailed knowledge of relevant dislocation core structures is lacking. Byhigh-resolution scanning transmission electron microscopy (STEM) of epitaxial single crystal (001)-oriented TiN films, we identify different dislocation types and their core structures. These include, besidesthe expected primary a/2{110}h110i dislocation, Shockley partial dislocations a/6{111}h112i and sessileLomer edge dislocations a/2{100}h011i. Density-functional theory and classical interatomic potentialsimulations complement STEM observations by recovering the atomic structure of the different disloca-tion types, estimating Peierls stresses, and providing insights on the chemical bonding nature at the core.The generated models of the dislocation cores suggest locally enhanced metal–metal bonding, weakenedTi-N bonds, and N vacancy-pinning that effectively reduces the mobilities of {110}h110i and {111}h112idislocations. Our findings underscore that the presence of different dislocation types and their effects onchemical bonding should be considered in the design and interpretations of nanoscale and macroscopicproperties of TiN.

Place, publisher, year, edition, pages
Elsevier, 2022
National Category
Other Materials Engineering
Identifiers
urn:nbn:se:liu:diva-190768 (URN)10.1016/j.matdes.2022.111327 (DOI)001013908300001 ()2-s2.0-85141335848 (Scopus ID)
Projects
FunMat-II
Funder
Uppsala University, 2009-00971Swedish Foundation for Strategic ResearchVinnova, 2016-05156Swedish Research Council, VR-2015-04630Knut and Alice Wallenberg Foundation, KAW-2018.0194
Note

Funding: Swedish Research Council [2017-03813, 2017-06701, 2021-04426, 202100357, 2019-00191]; VINNOVA [2016-05156]; Swedish government strategic research area grant AFM -SFO MatLiU [2009-00971]; Knut and Alice Wallenberg Foundation (Wallenberg Scholar grant) [KAW-2018.0194]; Swedish Research Council [2017-03813] Funding Source: Swedish Research Council

Available from: 2022-12-30 Created: 2022-12-30 Last updated: 2024-01-08Bibliographically approved
Gervilla, V., Zarshenas, M., Sangiovanni, D. G. & Sarakinos, K. (2020). Anomalous versus Normal Room-Temperature Diffusion of Metal Adatoms on Graphene. The Journal of Physical Chemistry Letters, 11(21), 8930-8936
Open this publication in new window or tab >>Anomalous versus Normal Room-Temperature Diffusion of Metal Adatoms on Graphene
2020 (English)In: The Journal of Physical Chemistry Letters, E-ISSN 1948-7185, The Journal of Physical Chemistry Letters, Vol. 11, no 21, p. 8930-8936Article in journal (Refereed) Published
Abstract [en]

Fabrication of high-performance heterostructure devices requires fundamental understanding of the diffusion dynamics of metal species on 2D materials. Here, we investigate the room-temperature diffusion of Ag, Au, Cu, Pd, Pt, and Ru adatoms on graphene using ab initio and classical molecular dynamics simulations. We find that Ag, Au, Cu, and Pd follow Lévy walks, in which adatoms move continuously within ∼1–4 nm2 domains during ∼0.04 ns timeframes, and they occasionally perform ∼2–4 nm flights across multiple surface adsorption sites. This anomalous diffusion pattern is associated with a flat (<50 meV) potential energy landscape (PEL), which renders surface vibrations important for adatom migration. The latter is not the case for Pt and Ru, which encounter a significantly rougher PEL (>100 meV) and, hence, migrate via conventional random walks. Thus, adatom anomalous diffusion is a potentially important aspect for modeling growth of metal films and nanostructures on 2D materials.

Place, publisher, year, edition, pages
Washington, DC, United States: American Chemical Society, 2020
National Category
Physical Chemistry
Identifiers
urn:nbn:se:liu:diva-171416 (URN)10.1021/acs.jpclett.0c02375 (DOI)000589920000001 ()32986445 (PubMedID)2-s2.0-85095799468 (Scopus ID)
Note

Funding agencies: Swedish research council (contract VR-2015-04630), ÅForsk foundation (contract ÅF 19-137), Olle Engkvist foundation (contract SOEB 190-312), Swedish Research Council through Grant Agreement No. VR-2015-04630

Available from: 2020-11-16 Created: 2020-11-16 Last updated: 2024-07-04Bibliographically approved
Jamnig, A., Sangiovanni, D. G., Abadias, G. & Sarakinos, K. (2019). Atomic-scale diffusion rates during growth of thin metal films on weakly-interacting substrates. Scientific Reports, 9, Article ID 6640.
Open this publication in new window or tab >>Atomic-scale diffusion rates during growth of thin metal films on weakly-interacting substrates
2019 (English)In: Scientific Reports, E-ISSN 2045-2322, Vol. 9, article id 6640Article in journal (Refereed) Published
Abstract [en]

We use a combined experimental and theoretical approach to study the rates of surface diffusion processes that govern early stages of thin Ag and Cu film morphological evolution on weakly-interacting amorphous carbon substrates. Films are deposited by magnetron sputtering, at temperatures T-S between 298 and 413 K, and vapor arrival rates F in the range 0.08 to 5.38 monolayers/s. By employing in situ and real-time sheet-resistance and wafer-curvature measurements, we determine the nominal film thickness Theta at percolation (Theta(perc)) and continuous film formation (Theta(cont)) transition. Subsequently, we use the scaling behavior of Theta(perc) and Theta(cont) as a function of F and T-s, to estimate, experimentally, the temperature-dependent diffusivity on the substrate surface, from which we calculate Ag and Cu surface migration energy barriers E-D(exp) and attempt frequencies nu(exp)(0). By critically comparing E-D(exp) and nu(exp)(0) with literature data, as well as with results from our ab initio molecular dynamics simulations for single Ag and Cu adatom diffusion on graphite surfaces, we suggest that: (i) E-D(exp) and nu(exp)(0) correspond to diffusion of multiatomic clusters, rather than to diffusion of monomers; and (ii) the mean size of mobile clusters during Ag growth is larger compared to that of Cu. The overall results of this work pave the way for studying growth dynamics in a wide range of technologically-relevant weakly-interacting film/substrate systems-including metals on 2D materials and oxides-which are building blocks in next-generation nanoelectronic, optoelectronic, and catalytic devices.

Place, publisher, year, edition, pages
Nature Publishing Group, 2019
National Category
Condensed Matter Physics
Identifiers
urn:nbn:se:liu:diva-158369 (URN)10.1038/s41598-019-43107-8 (DOI)000466127100065 ()31036908 (PubMedID)2-s2.0-85065068804 (Scopus ID)
Note

Funding Agencies|French Government program "Investissements dAvenir" (LABEX INTERACTIFS) [ANR-11-LABX-0017-01]; Linkoping University ("LiU Career Contract") [Dnr-LiU-2015-01510]; Swedish research council [VR-2015-04630]; Olle Engkvist foundation [SOEB 190-312]; Olle Engkvist Foundation

Available from: 2019-07-02 Created: 2019-07-02 Last updated: 2022-09-15Bibliographically approved
Edström, D., Sangiovanni, D. G., Landälv, L., Eklund, P., Greene, J. E., Petrov, I., . . . Chirita, V. (2019). Mechanical properties of VMoNO as a function of oxygen concentration: Toward development of hard and tough refractory oxynitrides. Journal of Vacuum Science & Technology. A. Vacuum, Surfaces, and Films, 37(6), Article ID 061508.
Open this publication in new window or tab >>Mechanical properties of VMoNO as a function of oxygen concentration: Toward development of hard and tough refractory oxynitrides
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2019 (English)In: Journal of Vacuum Science & Technology. A. Vacuum, Surfaces, and Films, ISSN 0734-2101, E-ISSN 1520-8559, Vol. 37, no 6, article id 061508Article in journal (Refereed) Published
Abstract [en]

Improved toughness is a central goal in the development of wear-resistant refractory ceramic coatings. Extensive theoretical and experimental research has revealed that NaCl-structure VMoN alloys exhibit surprisingly high ductility combined with high hardness and toughness. However, during operation, protective coatings inevitably oxidize, a problem that may compromise material properties and performance. Here, the authors explore the role of oxidation in altering VMoN properties. Density functional theory and theoretical intrinsic hardness models are used to investigate the mechanical behavior of cubic V0.5Mo0.5N1-xOx solid solutions as a function of the oxygen concentration x. Elastic constant and intrinsic hardness calculations show that oxidation does not degrade the mechanical properties of V0.5Mo0.5N. Electronic structure analyses indicate that the presence of oxygen reduces the covalent bond character, which slightly lowers the alloy strength and intrinsic hardness. Nevertheless, the character of metallic d-d states, which are crucial for allowing plastic deformation and enhancing toughness, remains unaffected. Overall, the authors results suggest that VMoNO oxynitrides, with oxygen concentrations as high as 50%, possess high intrinsic hardness, while still being ductile. Published by the AVS.

Place, publisher, year, edition, pages
A V S AMER INST PHYSICS, 2019
National Category
Inorganic Chemistry
Identifiers
urn:nbn:se:liu:diva-163046 (URN)10.1116/1.5125302 (DOI)000504231200029 ()
Note

Funding Agencies|Swedish Government Strategic Research Area Grant in Materials Science on Advanced Functional Materials at Linkoping University (Faculty Grant SFO-Mat-LiU) [2009 00971]; Olle Engkvist Foundation; competence center FunMat-II - Swedish Agency for Innovation Systems (Vinnova)Vinnova [2016-05156]

Available from: 2020-01-09 Created: 2020-01-09 Last updated: 2021-12-28
Almyras, G., Sangiovanni, D. G. & Sarakinos, K. (2019). Semi-Empirical Force-Field Model For The Ti1-XAlXN (0 ≤ x ≤ 1) System. Materials, 12(2), Article ID 215.
Open this publication in new window or tab >>Semi-Empirical Force-Field Model For The Ti1-XAlXN (0 ≤ x ≤ 1) System
2019 (English)In: Materials, E-ISSN 1996-1944, Vol. 12, no 2, article id 215Article in journal (Refereed) Published
Abstract [en]

We present a modified embedded atom method (MEAM) semi-empirical force-field model for the Ti1-xAlxN (0 x 1) alloy system. The MEAM parameters, determined via an adaptive simulated-annealing (ASA) minimization scheme, optimize the models predictions with respect to 0 K equilibrium volumes, elastic constants, cohesive energies, enthalpies of mixing, and point-defect formation energies, for a set of approximate to 40 elemental, binary, and ternary Ti-Al-N structures and configurations. Subsequently, the reliability of the model is thoroughly verified against known finite-temperature thermodynamic and kinetic properties of key binary Ti-N and Al-N phases, as well as properties of Ti1-xAlxN (0 amp;lt; x amp;lt; 1) alloys. The successful outcome of the validation underscores the transferability of our model, opening the way for large-scale molecular dynamics simulations of, e.g., phase evolution, interfacial processes, and mechanical response in Ti-Al-N-based alloys, superlattices, and nanostructures.

Place, publisher, year, edition, pages
MDPI, 2019
Keywords
titanium-aluminum nitride; Ti-Al-N; MD simulations; molecular dynamics; interatomic potential; MEAM; force-field model; spinodal decomposition; phase stability
National Category
Metallurgy and Metallic Materials
Identifiers
urn:nbn:se:liu:diva-155607 (URN)10.3390/ma12020215 (DOI)000459719000019 ()30634593 (PubMedID)
Note

Funding Agencies|Olle Engkvist foundation; competence center FunMat-II - Vinnova [2016-05156]; Linkoping University ("LiU Career Contract") [LiU-2015-01510]; Swedish research council [VR-2015-04630]; Olle Engkvist foundation [SOEB 190-312]

Available from: 2019-03-21 Created: 2019-03-21 Last updated: 2024-07-04
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ORCID iD: ORCID iD iconorcid.org/0000-0002-1379-6656

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