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Osikoya, A., Parlak, O., Murugan, N. .. r., Dikio, E. D., Moloto, H., Uzun, L., . . . Tiwari, A. (2017). Acetylene-sourced CVD-synthesised catalytically active graphene for electrochemical biosensing.. Biosensors & bioelectronics, 89, 496-504.
Open this publication in new window or tab >>Acetylene-sourced CVD-synthesised catalytically active graphene for electrochemical biosensing.
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2017 (English)In: Biosensors & bioelectronics, ISSN 0956-5663, E-ISSN 1873-4235, Vol. 89, 496-504 p.Article in journal (Refereed) Published
Abstract [en]

In this study, we have demonstrated the use of a graphene sheet as a fundamental building block to obtain a highly ordered graphene-enzyme electrode for electrochemical biosensing. Firstly, thin graphene sheets were deposited on 1.00 mm thick copper sheet at 850 oC, via chemical vapour deposition (CVD), using acetylene (C2H2) as carbon source in an argon (Ar) and nitrogen (N2) atmosphere. An anionic surfactant was used to introduce electrostatic charges and increase wettability and hydrophilicity on the basal plane of the otherwise hydrophobic graphene, thereby facilitating the assembly of biomolecules on the graphene surface. The bioelectrocatalytic activity of the system was investigated by the assembly of glucose oxidase (GOx) on the surface of the graphene sheet by intermolecular attractive forces. The electrochemical sensing activity of the graphene-based system was explored as a model for bioelectrocatalysis. The bioelectrode exhibited a linear response to glucose concentration from 0.2 to 9.8 mM, with sensitivity of 0.087 µA/µM/cm2 and a detection limit of 0.12 µM (S/N=3). This work sets the stage for the use of acetylene-sourced graphene sheets as fundamental building blocks in the fabrication of electrochemical biosensors and other biocatalytic devices.

Place, publisher, year, edition, pages
Elsevier, 2017
Keyword
CVD-graphene, bioelectronics, theoretical calculation, surfactant modification, 2D-materials
National Category
Condensed Matter Physics
Identifiers
urn:nbn:se:liu:diva-128195 (URN)10.1016/j.bios.2016.03.063 (DOI)000391077000048 ()27157880 (PubMedID)
Note

Funding agencies: Swedish Research Council, Sweden [VR-2011-6058357]; Research Directorate of the Vaal University of Technology, South Africa

Available from: 2016-05-20 Created: 2016-05-20 Last updated: 2017-11-30
Turner, A. (2017). Biosensors – Towards Frictionless Management of Health.. In: : . Paper presented at Joint conference of the European Medical and Biological Engineering Conference (EMBEC) and the Nordic-Baltic Conference on Biomedical Engineering and Medical Physics (NBC). Tampere, Finland, 11-15 June 2017.. EMBEC & NBC.
Open this publication in new window or tab >>Biosensors – Towards Frictionless Management of Health.
2017 (English)Conference paper, Oral presentation with published abstract (Refereed)
Place, publisher, year, edition, pages
EMBEC & NBC, 2017
National Category
Biological Sciences
Identifiers
urn:nbn:se:liu:diva-137658 (URN)
Conference
Joint conference of the European Medical and Biological Engineering Conference (EMBEC) and the Nordic-Baltic Conference on Biomedical Engineering and Medical Physics (NBC). Tampere, Finland, 11-15 June 2017.
Available from: 2017-05-23 Created: 2017-05-23 Last updated: 2017-06-15Bibliographically approved
Turner, A. (2017). Biosensors for diabetes: how far have we come?Asian Advanced Materials Congress 2017.. In: Asian Advanced Materials Congress 2017.: . Paper presented at Asian Advanced Materials Congress 2017. 11-16 March 2017, Singapore.. VBRI.
Open this publication in new window or tab >>Biosensors for diabetes: how far have we come?Asian Advanced Materials Congress 2017.
2017 (English)In: Asian Advanced Materials Congress 2017., VBRI , 2017Conference paper, Published paper (Refereed)
Place, publisher, year, edition, pages
VBRI, 2017
National Category
Biological Sciences
Identifiers
urn:nbn:se:liu:diva-137655 (URN)10.5185/asamc.2017 (DOI)
Conference
Asian Advanced Materials Congress 2017. 11-16 March 2017, Singapore.
Available from: 2017-05-23 Created: 2017-05-23 Last updated: 2017-06-02Bibliographically approved
Turner, A. (2017). Biosensors: how to achieve the ultimate in performance with the simplest of devices.: Cell Biology Plenary Lecture. In: : . Paper presented at Society for Experimental Biology (SEB Gothenburg 2017), Swedish Exhibition Centre, Gothenburg, Sweden. 3-6 July 2017. . Society for Experimental Biology, London..
Open this publication in new window or tab >>Biosensors: how to achieve the ultimate in performance with the simplest of devices.: Cell Biology Plenary Lecture
2017 (English)Conference paper, Oral presentation with published abstract (Refereed)
Place, publisher, year, edition, pages
. Society for Experimental Biology, London., 2017
National Category
Biological Sciences
Identifiers
urn:nbn:se:liu:diva-137659 (URN)
Conference
Society for Experimental Biology (SEB Gothenburg 2017), Swedish Exhibition Centre, Gothenburg, Sweden. 3-6 July 2017
Available from: 2017-05-23 Created: 2017-05-23 Last updated: 2017-06-15Bibliographically approved
Parlak, O., Mishra, Y. K., Grigoriev, A., Mecklenburg, M., Luo, W., Keene, S., . . . Tiwari, A. (2017). Hierarchical Aerographite Nano-Microtubular Tetrapodal Networks based Electrodes as Lightweight Supercapacitor.. Nano Energy, 34, 570-577.
Open this publication in new window or tab >>Hierarchical Aerographite Nano-Microtubular Tetrapodal Networks based Electrodes as Lightweight Supercapacitor.
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2017 (English)In: Nano Energy, ISSN 2211-2855, E-ISSN 2211-3282, Vol. 34, 570-577 p.Article in journal (Refereed) Published
Abstract [en]

A great deal of interest has been paid to the application of carbon-based nano- and microstructured materials as electrodes due to their relatively low-cost production, abundance, large surface area, high chemical stability, wide operating temperature range, and ease of processing including many more excellent features. The nanostructured carbon materials usually offer various micro-textures due to their varying degrees of graphitisation, a rich variety in terms of dimensionality as well as morphologies, extremely large surface accessibility and high electrical conductivity, etc. The possibilities of activating them by chemical and physical methods allow these materials to be produced with further higher surface area and controlled distribution of pores from nanoscale upto macroscopic dimensions, which actually play the most crucial role towards construction of the efficient electrode/electrolyte interfaces for capacitive processes in energy storage applications. Development of new carbon materials with extremely high surface areas could exhibit significant potential in this context and motivated by this in present work, we report for the first time the utilization of ultralight and extremely porous nano-microtubular Aerographite  tetrapodal network as a functional interface to probe the electrochemical properties for capacitive energy storage. A simple and robust electrode fabrication strategy based on surface functionalized Aerographite with optimum porosity leads to significantly high specific capacitance (640 F/g) with high energy (14.2 Wh/kg) and power densities (9.67x103 W/kg) which has been discussed in detail.

Place, publisher, year, edition, pages
Elsevier, 2017
Keyword
Hierarchical nanocarbons; tubular Aerographite; electrodes; porous interfaces; supercapacitors.
National Category
Materials Chemistry
Identifiers
urn:nbn:se:liu:diva-137651 (URN)10.1016/j.nanoen.2017.03.004 (DOI)000400383300061 ()2-s2.0-85015670974 (Scopus ID)
Funder
Knut and Alice Wallenberg Foundation, KAW 2014.0387
Available from: 2017-05-23 Created: 2017-05-23 Last updated: 2017-06-15Bibliographically approved
Korpan, Y. I., Turner, A. & El'skaya, A. (2017). Metabolomics on Electrodes – A New Evolutionary Step in Sensing and Sensitivity.. In: European Advanced Materials Congress 2017: . Paper presented at European Advanced Materials Congress 2017, Stockholm, Sweden.. VBRI.
Open this publication in new window or tab >>Metabolomics on Electrodes – A New Evolutionary Step in Sensing and Sensitivity.
2017 (English)In: European Advanced Materials Congress 2017, VBRI , 2017Conference paper, Oral presentation with published abstract (Refereed)
Place, publisher, year, edition, pages
VBRI, 2017
National Category
Medical Biotechnology
Identifiers
urn:nbn:se:liu:diva-137656 (URN)
Conference
European Advanced Materials Congress 2017, Stockholm, Sweden.
Available from: 2017-05-23 Created: 2017-05-23 Last updated: 2017-06-15Bibliographically approved
Turner, A. (2017). Single-molecule electroanalysis and printed electronic systems.. In: : . Paper presented at 5th International Conference on Bio-Sensing Technology, Riva Del Garda, Italy. 7-10 May 2017. Oxford, UK: Elsevier, Article ID 0014.
Open this publication in new window or tab >>Single-molecule electroanalysis and printed electronic systems.
2017 (English)Conference paper, Oral presentation with published abstract (Refereed)
Place, publisher, year, edition, pages
Oxford, UK: Elsevier, 2017
National Category
Biological Sciences
Identifiers
urn:nbn:se:liu:diva-137657 (URN)
Conference
5th International Conference on Bio-Sensing Technology, Riva Del Garda, Italy. 7-10 May 2017
Available from: 2017-05-23 Created: 2017-05-23 Last updated: 2017-06-15Bibliographically approved
Mishra, S., Ashaduzzaman, M., Mishra, P., Swart, H., Turner, A. & Tiwari, A. (2017). Stimuli-enabled zipper-like graphene interface for auto-switchable bioelectronics.. Biosensors & bioelectronics, 89, 305-311.
Open this publication in new window or tab >>Stimuli-enabled zipper-like graphene interface for auto-switchable bioelectronics.
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2017 (English)In: Biosensors & bioelectronics, ISSN 0956-5663, E-ISSN 1873-4235, Vol. 89, 305-311 p.Article in journal (Refereed) Published
Abstract [en]

Graphene interfaces with multi-stimuli responsiveness are of particular interest due to their diverse super-thin interfacial behaviour, which could be well suited to operating complex physiological systems in a single miniaturised domain. In general, smart graphene interfaces switch bioelectrodes from the hydrophobic to hydrophilic state, or vice versa, upon triggering. In the present work, a stimuli encoded zipper-like graphene oxide (GrO)/polymer interface was fabricated with in situ poly(N-isopropylacrylamide–co–diethylaminoethylmethylacrylate), i.e., poly(NIPAAm–co–DEAEMA) directed hierarchical self-assembly of GrO and glucose oxidase (GOx). The designed interface exhibited reversible on/off-switching of bio-electrocatalysis on changing the pH between 5 and 8, via phase transition from super hydrophilic to hydrophobic. The study further indicated that the zipper-like interfacial bioelectrochemical properties could be tuned over a modest change of temperature (i.e., 20–40 °C). The resulting auto-switchable interface has implications for the design of novel on/off-switchable biodevices with ‘in-built’ self-control.

Place, publisher, year, edition, pages
Elsevier, 2017
Keyword
Triggered interfaces; Graphene bioelectronics; Smart Bioelectrocatalysis; On/off-switchable bio-devices
National Category
Condensed Matter Physics
Identifiers
urn:nbn:se:liu:diva-128196 (URN)10.1016/j.bios.2016.03.052 (DOI)000391077000023 ()27132998 (PubMedID)
Available from: 2016-05-20 Created: 2016-05-20 Last updated: 2017-11-30
Sekretaryova, A., Eriksson, M. & Turner, A. (2016). Bioelectrocatalytic systems for health applications. Biotechnology Advances, 34(3), 177-197.
Open this publication in new window or tab >>Bioelectrocatalytic systems for health applications
2016 (English)In: Biotechnology Advances, ISSN 0734-9750, E-ISSN 1873-1899, Vol. 34, no 3, 177-197 p.Article, review/survey (Refereed) Published
Abstract [en]

We present a brief overview of bioelectrocatalytic devices for in vitro health applications, including food safety and environmental analysis, focusing on microelectrode- and microfluidic-based biosensors, paper-based point-of-care devices and wearable biosensors. The main hurdles and future perspectives are discussed. We then consider the role of electron transfer between a biocatalyst and an electrode in biosensor design. Brief descriptions of indirect, direct and mediated mechanisms are given. The principal strategies, as well as recent developments for modulation of electron transfer in biocatalytic systems are summarised. In conclusion, we highlight some of the challenges associated with improving these redox systems.

Place, publisher, year, edition, pages
Elsevier, 2016
Keyword
Direct electron transfer; Mediated electron transfer; Immobilisation; Microbiosensor; Nanobiosensor; Paper-based biosensor; Wearable biosensor; Self-powered biosensor
National Category
Bioinformatics and Systems Biology
Identifiers
urn:nbn:se:liu:diva-123688 (URN)10.1016/j.biotechadv.2015.12.005 (DOI)000375500700004 ()26724183 (PubMedID)
Available from: 2016-01-08 Created: 2016-01-08 Last updated: 2017-12-01Bibliographically approved
Azzouzi, S., Patra, H. K., Ben Ali, M., Nooredeen Abbas, M., Dridi, C., Errachid, A. & Turner, A. (2016). Citrate-selective electrochemical mu-sensor for early stage detection of prostate cancer. Sensors and actuators. B, Chemical, 228, 335-346.
Open this publication in new window or tab >>Citrate-selective electrochemical mu-sensor for early stage detection of prostate cancer
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2016 (English)In: Sensors and actuators. B, Chemical, ISSN 0925-4005, E-ISSN 1873-3077, Vol. 228, 335-346 p.Article in journal (Refereed) Published
Abstract [en]

The extremely specialised anatomical function of citrate inside the prostate, make it one of the preferred biomarkers for early stage detection of prostate cancer. However, current detection methods are seriously limited due to the very low citrate concentrations that need to be measured in order to follow disease progression. In the present work, we report a novel citrate-selective-sensor based on iron (III) phthalocyanine chloride-C-monoamido-Poly-n-Butyl Acrylate (Fe(III)MAPcC1 P n BA) modified gold -electrodes for the electrochemical determination and estimation of the pathophysiological range of citrate. The newly synthesised ionophore has been structurally characterised using Fourier transform infrared (FTIR) and UV-vis spectroscopy. Contact angle measurements and atomic force microscopy (AFM) have been used to investigate the adhesion and morphological properties of the membrane. The developed citrate-selective-electrodes had a Nernstian sensitivity of-19.34 +/- 0.83 mV/decade with a detection limit of about 9 x 10-6M and a linear range from 4 x 10(-5)M to 10(-1) M, which covered the pathologically important clinical range. Electrochemical impedance spectroscopy (EIS) showed very high sensitivity with a lower Limit of detection 1.7 x 10(-9) M and linear detection range (10(-8)-10(-1) M), which is very important not only for the early-stage diagnosis and screening procedures, but also in mapping the stage of the cancer too. (C) 2016 Elsevier B.V. All rights reserved.

Place, publisher, year, edition, pages
ELSEVIER SCIENCE SA, 2016
Keyword
Citrate selective ionophore; Potentiometry; Impedance spectroscopy; Prostate cancer; Early-stage detection
National Category
Medical Laboratory and Measurements Technologies Analytical Chemistry
Identifiers
urn:nbn:se:liu:diva-126791 (URN)10.1016/j.snb.2016.01.056 (DOI)000371027900045 ()
Note

Funding Agencies|NATO Science for Peace (SFP) Project [CBP.NUKR.SFP 984173]; FP7-PEOPLE-IRSES [318053]; SEA-on-a-Chip project [614168]

Available from: 2016-04-07 Created: 2016-04-05 Last updated: 2017-11-30
Organisations
Identifiers
ORCID iD: ORCID iD iconorcid.org/0000-0002-1815-9699

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