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Copper-phthalocyanine encapsulated into zeolite-Y with high Si/Al: An EPR study
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2005 (engelsk)Inngår i: Chemical Physics Letters, ISSN 0009-2614, E-ISSN 1873-4448, Vol. 415, nr 1-3, s. 126-130Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Copper (II) phthalocyanine (CuPc) molecules encapsulated into zeolite-Y with Si/Al ratios of 2.7 and 410 were prepared by an in situ synthesis and characterized by UV-Vis and electron paramagnetic resonance (EPR) spectroscopies. Resolved Cu-hyperfine and N-superhyperfine structures were observed in the EPR spectrum of CuPc encapsulated into zeolite-Y with a high Si/Al ratio. UV-Vis and EPR studies as well as theoretical calculations suggest that the encapsulated CuPc molecule was distorted in zeolite-Y with keeping of the square-planar symmetry around the center copper (II) ion. © 2005 Elsevier B.V. All rights reserved.

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2005. Vol. 415, nr 1-3, s. 126-130
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URN: urn:nbn:se:liu:diva-33714DOI: 10.1016/j.cplett.2005.08.140Lokal ID: 19755OAI: oai:DiVA.org:liu-33714DiVA, id: diva2:254537
Tilgjengelig fra: 2009-10-09 Laget: 2009-10-09 Sist oppdatert: 2017-12-13

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