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Electrolyte-Gated Organic Thin-Film Transistors
Linköpings universitet, Institutionen för teknik och naturvetenskap. Linköpings universitet, Tekniska högskolan. (Organic Electronics)
2011 (engelsk)Doktoravhandling, med artikler (Annet vitenskapelig)
Abstract [en]

There has been a remarkable progress in the development of organic electronic materials since the discovery of conducting polymers more than three decades ago. Many of these materials can be processed from solution, in the form as inks. This allows for using traditional high-volume printing techniques for manufacturing of organic electronic devices on various flexible surfaces at low cost. Many of the envisioned applications will use printed batteries, organic solar cells or electromagnetic coupling for powering. This requires that the included devices are power efficient and can operate at low voltages.

This thesis is focused on organic thin-film transistors that employ electrolytes as gate insulators. The high capacitance of the electrolyte layers allows the transistors to operate at very low voltages, at only 1 V. Polyanion-gated p-channel transistors and polycation-gated n-channel transistors are demonstrated. The mobile ions in the respective polyelectrolyte are attracted towards the gate electrode during transistor operation, while the polymer ions create a stable interface with the charged semiconductor channel. This suppresses electrochemical doping of the semiconductor bulk, which enables the transistors to fully operate in the field-effect mode. As a result, the transistors display relatively fast switching (≤ 100 µs). Interestingly, the switching speed of the transistors saturates as the channel length is reduced. This deviation from the downscaling rule is explained by that the ionic relaxation in the electrolyte limits the channel formation rather than the electronic transport in the semiconductor. Moreover, both unipolar and complementary integrated circuits based on polyelectrolyte-gated transistors are demonstrated. The complementary circuits operate at supply voltages down to 0.2 V, have a static power consumption of less than 2.5 nW per gate and display signal propagation delays down to 0.26 ms per stage. Hence, polyelectrolyte-gated circuits hold great promise for printed electronics applications driven by low-voltage and low-capacity power sources.

sted, utgiver, år, opplag, sider
Linköping: Linköping University Electronic Press , 2011. , s. 62
Serie
Linköping Studies in Science and Technology. Dissertations, ISSN 0345-7524 ; 1389
Emneord [en]
Organic electronics, Thin-film transistor, Organic semiconductor, Polymer, Electrolyte, Polyelectrolyte
HSV kategori
Identifikatorer
URN: urn:nbn:se:liu:diva-69636ISBN: 978-91-7393-088-8 (tryckt)OAI: oai:DiVA.org:liu-69636DiVA, id: diva2:432465
Disputas
2011-08-26, K3, Kåkenhus, Campus Norrköping, Linköpings universitet, Norrköping, 10:15 (engelsk)
Opponent
Veileder
Tilgjengelig fra: 2011-08-15 Laget: 2011-07-08 Sist oppdatert: 2019-12-19bibliografisk kontrollert
Delarbeid
1. Low-Voltage Polymer Field-Effect Transistors Gated via a Proton Conductor
Åpne denne publikasjonen i ny fane eller vindu >>Low-Voltage Polymer Field-Effect Transistors Gated via a Proton Conductor
Vise andre…
2007 (engelsk)Inngår i: Advanced Materials, ISSN 0935-9648, E-ISSN 1521-4095, Vol. 19, nr 1, s. 97-101Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Low operating voltages for p-channel organic field-effect transistors (OFETs) can be achieved by using an electrolyte as the gate insulator. However, mobile anions in the electrolyte can lead to undesired electrochemistry in the channel. In order to avoid this, a polyanionic electrolyte is used as the gate insulator. The resulting OFET has operating voltages of less than 1 V (see figure) and shows fast switching (less than 0.3 ms) in ambient atmosphere.

sted, utgiver, år, opplag, sider
Wiley Online, 2007
Emneord
Field-effect transistors, polymer ¿ Photolithography ¿ Polyelectrolytes ¿ Polymers
HSV kategori
Identifikatorer
urn:nbn:se:liu:diva-37442 (URN)10.1002/adma.200600871 (DOI)35829 (Lokal ID)35829 (Arkivnummer)35829 (OAI)
Tilgjengelig fra: 2009-10-10 Laget: 2009-10-10 Sist oppdatert: 2023-12-06bibliografisk kontrollert
2. Downscaling of Organic Field-Effect Transistors with a Polyelectrolyte Gate Insulator
Åpne denne publikasjonen i ny fane eller vindu >>Downscaling of Organic Field-Effect Transistors with a Polyelectrolyte Gate Insulator
Vise andre…
2008 (engelsk)Inngår i: Advanced Materials, ISSN 0935-9648, E-ISSN 1521-4095, Vol. 20, nr 24, s. 4708-4713Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

A polyelectrolyte is used as gate insulator material in organic field-effect transistors with self-aligned inkjet printed sub–micrometer channels. The small separation of the charges in the electric double layer at the electrolyte-semiconductor interface, which builds up in tens of microseconds, provides a very high transverse electric field in the channel that effectively suppresses short-channel effects at low applied gate voltages.

sted, utgiver, år, opplag, sider
Wiley Online, 2008
Emneord
Nanotechnology, Organic electronics, Organic field-effect transistors, Polyelectrolytes, Printed electronics
HSV kategori
Identifikatorer
urn:nbn:se:liu:diva-43272 (URN)10.1002/adma.200801756 (DOI)73282 (Lokal ID)73282 (Arkivnummer)73282 (OAI)
Tilgjengelig fra: 2009-10-10 Laget: 2009-10-10 Sist oppdatert: 2023-12-06bibliografisk kontrollert
3. Low-Voltage Ring Oscillators Based on Polyelectrolyte-Gated Polymer Thin-Film Transistors
Åpne denne publikasjonen i ny fane eller vindu >>Low-Voltage Ring Oscillators Based on Polyelectrolyte-Gated Polymer Thin-Film Transistors
Vise andre…
2010 (engelsk)Inngår i: Advanced Materials, ISSN 0935-9648, E-ISSN 1521-4095, Vol. 22, nr 1, s. 72-76Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

A polyanionic electrolyte is used as gate insulator in top-gate p-channel polymer thin-film transistors. The high capacitance of the polyelectrolyte film allows the transistors and integrated circuits to operate below 1.5 V. Seven-stage ring oscillators that operate at supply voltages down to 0.9 V and exhibit signal propagation delays as low as 300 µs per stage are reported.

Emneord
organic electronics, oscillators, polyelectrolytes, thin-film transistors
HSV kategori
Identifikatorer
urn:nbn:se:liu:diva-53026 (URN)10.1002/adma.200901850 (DOI)
Tilgjengelig fra: 2010-01-14 Laget: 2010-01-14 Sist oppdatert: 2023-12-06bibliografisk kontrollert
4. Polyelectrolyte-Gated Organic Complementary Circuits Operating at Low Power and Voltage
Åpne denne publikasjonen i ny fane eller vindu >>Polyelectrolyte-Gated Organic Complementary Circuits Operating at Low Power and Voltage
2011 (engelsk)Inngår i: Advanced Materials, ISSN 0935-9648, E-ISSN 1521-4095, Vol. 23, nr 40, s. 4684-Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

In this work, polyanionic and polycationic electrolytes are used as gate insulators in p- and n-channel thin-film transistors, respectively. These material combinations are motivated by that the mobile ions in the electrolytes will be attracted to the oppositely charged gate electrodes when the transistors are operated in the accumulation mode. The electronic charges in the semiconductor channels will thus be balanced by the polyions, which are effectively immobile and cannot penetrate into the semiconductor bulk and cause electrochemical doping.

sted, utgiver, år, opplag, sider
Wiley-Blackwell, 2011
Emneord
Organic electronics, Conjugated polymers, Polyelectrolytes, Thin-film transistors, Oscillators
HSV kategori
Identifikatorer
urn:nbn:se:liu:diva-69638 (URN)10.1002/adma.201101757 (DOI)000297009000014 ()
Merknad
Funding agencies|EU| 212311 |Swedish Government (Advanced Functional Materials)||Swedish Foundation for Strategic Research (OPEN)||Knut and Alice Wallenberg Foundation||Onnesjo Foundation||Tilgjengelig fra: 2011-07-08 Laget: 2011-07-08 Sist oppdatert: 2023-12-06bibliografisk kontrollert
5. Fiber-Embedded Electrolyte-Gated Field-Effect Transistors for e-Textiles
Åpne denne publikasjonen i ny fane eller vindu >>Fiber-Embedded Electrolyte-Gated Field-Effect Transistors for e-Textiles
Vise andre…
2009 (engelsk)Inngår i: Advanced Materials, ISSN 0935-9648, E-ISSN 1521-4095, Vol. 21, nr 5, s. 573-577Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Electrolyte-gate organic field-effect transistors embedded at the junction of textile microfibers are demonstrated. The fiber transistor operates below I V and delivers large current densities. The transience of the organic thin-film transistors current and the impedance spectroscopy measurements reveal that the channel is formed in two steps.

Emneord
Conducting polymers, electronic textile, fiber transistor, field-effect transistor
HSV kategori
Identifikatorer
urn:nbn:se:liu:diva-16982 (URN)10.1002/adma.200802681 (DOI)
Tilgjengelig fra: 2009-03-01 Laget: 2009-02-27 Sist oppdatert: 2023-12-06bibliografisk kontrollert
6. A Water-Gate Organic Field-Effect Transistor
Åpne denne publikasjonen i ny fane eller vindu >>A Water-Gate Organic Field-Effect Transistor
Vise andre…
2010 (engelsk)Inngår i: Advanced Materials, ISSN 0935-9648, E-ISSN 1521-4095, Vol. 22, nr 23, s. 2565-2569Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

High-dielectric-constant insulators, organic monolayers, and electrolytes have been successfully used to generate organic field-effect transistors operating at low voltages. Here, we report on a device gated with pure water. By replacing the gate dielectric by a simple water droplet, we produce a transistor that entirely operates in the field-effect mode of operation at voltages lower than 1V. This result creates opportunities for sensor applications using water-gated devices as transducing medium.

sted, utgiver, år, opplag, sider
John Wiley and Sons, Ltd, 2010
HSV kategori
Identifikatorer
urn:nbn:se:liu:diva-58247 (URN)10.1002/adma.200904163 (DOI)000279711100014 ()
Tilgjengelig fra: 2010-08-10 Laget: 2010-08-09 Sist oppdatert: 2023-12-06bibliografisk kontrollert

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