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Synthesis, Crystal Structure and Nonlinear Optical Properties of Nickel(Ⅱ) Complex with Schiff-base Ligand
Department of Chemistry, Anhui University, Chína.
Department of Chemistry, Anhui University, Chína.
Department of Chemistry, Anhui University, Chína.
Department of Chemistry, Anhui University, Chína.
Vise andre og tillknytning
2003 (engelsk)Inngår i: Chinese journal of structural chemistry, ISSN 0254-5861, Vol. 22, nr 3, s. 265-269Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The nickel(Ⅱ) complex with the new ligand of S-benzyl-β-N-[10-ethylphenothiazine-3-methylene]dithiocarbazate(HL) crystallizes in the triclinic system, space group P1-with a = 7.516(1), b = 11.322(1), c = 13.366(1) (A),α= 84.818(1),β= 81.688(1), y= 76.037(1)°, V= 1090.26(3) (A)3, Z = 1, Dc=1.413 g/cm3, F(000) = 482,μ(MoKα)= 0.774 mm-1 (λ= 0.7103(A)),R = 0.0573 and wR =0.1375 for 3357 observed reflections withⅠ≥ 2σ(Ⅰ). The HL has lost a proton from its tautomeric thiol form and acts as a single negatively charged bidentate ligand coordinating to the nickel ion via the mercapto sulfur and β-nitrogen atoms. The geometry around Ni(Ⅱ) is almost square-planar with two equivalent Ni-N and Ni-S bonds. The nonlinear absorption of HL and NiL2 solutions (in DMF) was measured by open-aperture Z-scan technique at the wavelength of 532 nm.

sted, utgiver, år, opplag, sider
2003. Vol. 22, nr 3, s. 265-269
Emneord [en]
Crystal structure, nickel complex, NLO
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Identifikatorer
URN: urn:nbn:se:liu:diva-90652DOI: 10.3969/j.issn.0254-5861.2003.03.004OAI: oai:DiVA.org:liu-90652DiVA, id: diva2:614044
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Chinese journal title: Jiegou Huaxue

Tilgjengelig fra: 2013-04-03 Laget: 2013-04-03 Sist oppdatert: 2013-04-12

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