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Stresses and Cracking During Chromia-Spinel- NiO Cluster Formation in TBC Systems
Siemens Industrial Turbomachinery AB, Berlin, Germany.
University West, Trollhättan, Sweden.
Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska fakulteten.ORCID-id: 0000-0003-3277-1945
Linköpings universitet, Institutionen för ekonomisk och industriell utveckling, Konstruktionsmaterial. Linköpings universitet, Tekniska fakulteten.
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2015 (engelsk)Inngår i: Journal of thermal spray technology (Print), ISSN 1059-9630, E-ISSN 1544-1016, Vol. 24, nr 6, s. 1002-1014Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Thermal barrier coatings (TBC) are used in gas turbines to reduce the temperatures in the underlying substrate. There are several mechanisms that may cause the TBC to fail; one of them is cracking in the coating interface due to extensive oxidation. In the present study, the role of so called chromia-spinel-NiO (CSN) clusters in TBC failure was studied. Such clusters have previously been found to be prone to cracking. Finite element modeling was performed on a CSN cluster to find out at which stage of its formation it cracks and what the driving mechanisms of cracking are. The geometry of a cluster was obtained from micrographs and modeled as close as possible. Nanoindentation was performed on the cluster to get the correct Young’s moduli. The volumetric expansion associated with the formation of NiO was also included. It was found that the cracking of the CSN clusters is likely to occur during its last stage of formation as the last Ni-rich core oxidizes. Furthermore, it was shown that the volumetric expansion associated with the oxidation only plays a minor role and that the main reason for cracking is the high coefficient of thermal expansion of NiO.

sted, utgiver, år, opplag, sider
Springer, 2015. Vol. 24, nr 6, s. 1002-1014
Emneord [en]
chromia-spinel-NiO, failure mechnism, finite element modeling, oxide cluster, thermal barrier coating
HSV kategori
Identifikatorer
URN: urn:nbn:se:liu:diva-120423DOI: 10.1007/s11666-015-0270-yISI: 000358965400012OAI: oai:DiVA.org:liu-120423DiVA, id: diva2:844882
Tilgjengelig fra: 2015-08-10 Laget: 2015-08-10 Sist oppdatert: 2017-12-04

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