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Ternary Organic Solar Cells with Minimum Voltage Losses
Linköpings universitet, Institutionen för fysik, kemi och biologi, Ytors Fysik och Kemi. Linköpings universitet, Tekniska fakulteten.
Division of Chemical Physics, Lund University, Lund, Sweden.
State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an, China.
Linköpings universitet, Institutionen för fysik, kemi och biologi, Biomolekylär och Organisk Elektronik. Linköpings universitet, Tekniska fakulteten.
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2017 (Engelska)Ingår i: Advanced Energy Materials, ISSN 1614-6840, Vol. 7, nr 21, artikel-id 1700390Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

A new strategy for designing ternary solar cells is reported in this paper. A low-bandgap polymer named PTB7-Th and a high-bandgap polymer named PBDTTS-FTAZ sharing the same bulk ionization potential and interface positive integer charge transfer energy while featuring complementary absorption spectra are selected. They are used to fabricate efficient ternary solar cells, where the hole can be transported freely between the two donor polymers and collected by the electrode as in one broadband low bandgap polymer. Furthermore, the fullerene acceptor is chosen so that the energy of the positive integer charge transfer state of the two donor polymers is equal to the energy of negative integer charge transfer state of the fullerene, enabling enhanced dissociation of all polymer donor and fullerene acceptor excitons and suppressed bimolecular and trap assistant recombination. The two donor polymers feature good miscibility and energy transfer from high-bandgap polymer of PBDTTS-FTAZ to low-bandgap polymer of PTB7-Th, which contribute to enhanced performance of the ternary solar cell.

Ort, förlag, år, upplaga, sidor
John Wiley & Sons, 2017. Vol. 7, nr 21, artikel-id 1700390
Nyckelord [en]
binary equivalent, minimum voltage losses, same bulk and interface energy, ternary solar cells
Nationell ämneskategori
Polymerkemi
Identifikatorer
URN: urn:nbn:se:liu:diva-143026DOI: 10.1002/aenm.201700390ISI: 000414711100002Scopus ID: 2-s2.0-85025441174OAI: oai:DiVA.org:liu-143026DiVA, id: diva2:1157249
Anmärkning

Funding agencies: Knut and Alice Wallenberg Foundation; Swedish Research Council [2016-05498]; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoping University (Faculty Grant SFO Mat LiU) [2009 00971]; Goran Gustafsson Foundat

Tillgänglig från: 2017-11-15 Skapad: 2017-11-15 Senast uppdaterad: 2017-12-05Bibliografiskt granskad
Ingår i avhandling
1. Electronic Structure of π-Conjugated Materials and Their Effect on Organic Photovoltaics
Öppna denna publikation i ny flik eller fönster >>Electronic Structure of π-Conjugated Materials and Their Effect on Organic Photovoltaics
2017 (Engelska)Doktorsavhandling, sammanläggning (Övrigt vetenskapligt)
Abstract [en]

The great tunability of structure and electronic properties of π-conjugated organic molecules/polymers combined with other advantages such as light weight and flexibility etc., have made organic-based electronics the focus of an exciting still-growing field of physics and chemistry for more than half a century. The application of organic electronics has led to the appearance of wide range of organic electronic devices mainly including organic light emitting diodes (OLED), organic field effect transistors (OFET) and organic solar cells (OSC). The application of the organic electronic devices mainly is limited by two dominant parameters, i.e., their performance and stability. Up to date, OLED has been successfully commercialized in the market while the OSC are still on the way to commercialization hindered by low efficiency and inferior stability. Understanding the energy levels of organic materials and energy level alignment of the devices is crucial to control the efficiency and stability of the OSC. In this thesis, energy levels measured by different methods are studied to explore their relationship with device properties, and the strategies on how to design efficient and stable OSC based on energy level diagrams are provided.

Cyclic Voltammetry (CV) is a traditional and widely used method to probe the energy levels of organic materials, although there is little consensus on how to relate the oxidation/reduction potential ((Eox/Ered) to the vacuum level. Ultraviolet Photoelectron Spectroscopy (UPS) can be used to directly detect vertical ionization potential (IP) of organic materials. In this thesis, a linear relationship of IP and Eox was found, with a slope equal to unity. The relationship provides for easy conversion of values obtained by the two techniques, enabling complementarily use in designing and fabricating efficient and stable OSC. A popular rule of thumb is that the offset between the LUMO levels of donor and acceptor should be 0.3 eV, according to which a binary solar cell with the minimum voltage losses around 0.49 V was designed here.

Introduction of the ternary blend as active layer is an efficient way to improve both efficiency and stability of the OSC. Based on our studied energy-level diagram within the integer charge transfer (ICT) model, we designed ternary solar cells with enhanced open circuit voltage for the first time and improved thermal stability compared to reference binary ones. The ternary solar cell with minimum voltage losses was developed by combining two donor materials with same ionization potential and positive ICT energy while featuring complementary optical absorption. Furthermore, the fullerene acceptor was chosen so that the energy of the positive ICT state of the two donor polymers is equal to the energy of negative ICT state of the fullerene, which can enhance dissociation of all polymer donor and fullerene acceptor excitons and suppress bimolecular and trap-assistant recombination.

Rapid development of non-fullerene acceptors in the last two years affords more recipes of designing both efficient and stabile OSC. We show in this thesis how non-fullerene acceptors successfully can be used to design ternary solar cells with both enhanced efficiency and thermal stability. Besides improving the efficiency of the devices, understanding of the stability and degradation mechanism is another key issue. The degradation of conjugated molecules/polymers often follow many complicated pathways and at the same time many factors for degradation are coupled with each other. Therefore, the degradation of non-fullerene acceptors was investigated in darkness by photoelectron spectroscopy in this thesis with the in-situ method of controlling exposure of O2 and water vapor separately.

Ort, förlag, år, upplaga, sidor
Linköping: Linköping University Electronic Press, 2017. s. 84
Serie
Linköping Studies in Science and Technology. Dissertations, ISSN 0345-7524 ; 1893
Nationell ämneskategori
Annan elektroteknik och elektronik Den kondenserade materiens fysik Fysikalisk kemi
Identifikatorer
urn:nbn:se:liu:diva-143025 (URN)10.3384/diss.diva-143025 (DOI)9789176853931 (ISBN)
Disputation
2017-12-08, Schrödinger, Fysikhuset, Campus Valla, Linköping, 10:15 (Engelska)
Opponent
Handledare
Tillgänglig från: 2017-11-15 Skapad: 2017-11-15 Senast uppdaterad: 2019-10-12Bibliografiskt granskad

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