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Evaluating gas chromatography with a halogen-specific detectorfor the determination of disinfection by-products in drinking water
Linköpings universitet, Institutionen för tema, Tema Miljöförändring. Linköpings universitet, Filosofiska fakulteten.ORCID-id: 0000-0002-7422-0853
Linköpings universitet, Institutionen för tema, Tema Miljöförändring. Linköpings universitet, Filosofiska fakulteten.
Department of Chemistry, University of Dhaka, Dhaka, Bangladesh.ORCID-id: 0000-0002-9486-2749
Linköpings universitet, Institutionen för tema, Tema Miljöförändring. Linköpings universitet, Filosofiska fakulteten.ORCID-id: 0000-0002-2728-0941
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2019 (Engelska)Ingår i: Environmental science and pollution research international, ISSN 0944-1344, E-ISSN 1614-7499, Vol. 26, s. 7305-7314Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

The occurrence of disinfection by-products (DBPs) in drinking water has become an issue of concern during the past decades. The DBPs pose health risks and are suspected to cause various cancer forms, be genotoxic and have negative developmental effects. The vast chemical diversity of DBPs makes comprehensive monitoring challenging. Only few of the DBPs are regulated and included in analytical protocols. In this study, a method for simultaneous measurement of 20 DBPs from five different structural classes (both regulated and non-regulated) was investigated and further developed for 11 DBPs using solid phase extraction and gas chromatography coupled with a halogen specific detector (XSD). The XSD was highly selective towards halogenated DBPs, providing chromatograms with little noise. The method allowed detection down to 0.05 µg/L and showed promising results for the simultaneous determination of a range of neutral DBP classes. Compounds from two classes of emerging DBPs, more cytotoxic than the “traditional” regulated DBPs, were successfully determined using this method. However, haloacetic acids (HAAs) should be analyzed separately as some HAA methyl esters may degrade giving false positives of trihalomethanes (THMs). The method was tested on real water samples from two municipal waterworks where the target DBP concentrations were found below the regulatory limits of Sweden.

Ort, förlag, år, upplaga, sidor
Springer Berlin/Heidelberg, 2019. Vol. 26, s. 7305-7314
Nyckelord [en]
Drinking water, Disinfection by-products, Trihalomethanes, Haloacetic acids, Haloacetonitriles, Halogen-specific detector
Nationell ämneskategori
Analytisk kemi Miljövetenskap Oceanografi, hydrologi och vattenresurser
Identifikatorer
URN: urn:nbn:se:liu:diva-145402DOI: 10.1007/s11356-018-1419-2ISI: 000463824600002PubMedID: 29492811OAI: oai:DiVA.org:liu-145402DiVA, id: diva2:1186409
Forskningsfinansiär
Forskningsrådet Formas, 2013-1077
Anmärkning

Funding agencies: Swedish Research Council for Sustainable Development, FORMAS [2013-1077]

Tillgänglig från: 2018-02-28 Skapad: 2018-02-28 Senast uppdaterad: 2019-06-04Bibliografiskt granskad

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Evaluating gas chromatography with a halogen-specific detectorfor the determination of disinfection by-products in drinking water(804 kB)27 nedladdningar
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Andersson, AnnaAshiq, Muhammad JamshaidKarlsson, SusanneBastviken, DavidKylin, Henrik

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Andersson, AnnaAshiq, Muhammad JamshaidShoeb, MohammadKarlsson, SusanneBastviken, DavidKylin, Henrik
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