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Layered ternary M(n+1)AX(n) phases and their 2D derivative MXene: an overview from a thin-film perspective
Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska fakulteten.ORCID-id: 0000-0003-1785-0864
Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska fakulteten.
Linköpings universitet, Institutionen för fysik, kemi och biologi, Tunnfilmsfysik. Linköpings universitet, Tekniska fakulteten.ORCID-id: 0000-0001-9140-6724
2017 (engelsk)Inngår i: Journal of Physics D: Applied Physics, ISSN 0022-3727, E-ISSN 1361-6463, Vol. 50, nr 11, artikkel-id 113001Artikkel, forskningsoversikt (Fagfellevurdert) Published
Abstract [en]

Inherently and artificially layered materials are commonly investigated both for fundamental scientific purposes and for technological application. When a layered material is thinned or delaminated to its physical limits, a two-dimensional (2D) material is formed and exhibits novel properties compared to its bulk parent phase. The complex layered phases known as MAX phases (where M = early transition metal, A = A-group element, e.g. Al or Si, and X = C or N) are an exciting model system for materials design and the understanding of process-structure-property relationships. When the A layers are selectively etched from the MAX phases, a new type of 2D material is formed, named MXene to emphasize the relation to the MAX phases and the parallel with graphene. Since their discovery in 2011, MXenes have rapidly become established as a novel class of 2D materials with remarkable possibilities for composition variations and property tuning. This article gives a brief overview of MAX phases and MXene from a thin-film perspective, reviewing theory, characterization by electron microscopy, properties and how these are affected by the change in dimensionality, and outstanding challenges.

sted, utgiver, år, opplag, sider
IOP PUBLISHING LTD , 2017. Vol. 50, nr 11, artikkel-id 113001
Emneord [en]
Ti3SiC2; physical vapor deposition; sputtering; electron microscopy; MXene; ceramics; 2D materials
HSV kategori
Identifikatorer
URN: urn:nbn:se:liu:diva-136890DOI: 10.1088/1361-6463/aa57bcISI: 000398854900001OAI: oai:DiVA.org:liu-136890DiVA, id: diva2:1092063
Merknad

Funding Agencies|European Research Council under the European Communitys Seventh Framework Programme (FP) ERC [335383, 258509]; knut and Alice Wallenberg Foundation through the Wallenberg Academy Fellows program; electron microscopy laboratory in Linkoping; Swedish Research Council (VR) [621-2012-4430, 6212012-4425, 642-2013-8020, 621-2012-4359, 622-2008405]; Swedish Foundation for Strategic Research (SSF) through the Synergy Grant FUNCASE; Future Research Leaders 5 program (PE); Swedish Government-Strategic Research Area in Materials Science on Functional Materials at Linkoping University [2009-00971]; Research Infrastructure Fellow program (POAP)

Tilgjengelig fra: 2017-04-29 Laget: 2017-04-29 Sist oppdatert: 2017-05-21

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