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Poly(3,4-ethylenedioxythiophene)-Tosylate (PEDOT-Tos) electrode in Thermogalvanic Cells
Linköping University, Department of Science and Technology, Physics and Electronics. Linköping University, Faculty of Science & Engineering.
Linköping University, Department of Science and Technology, Physics and Electronics. Linköping University, Faculty of Science & Engineering.ORCID iD: 0000-0001-8478-4663
Linköping University, Department of Science and Technology. Linköping University, Faculty of Science & Engineering.
Linköping University, Department of Science and Technology, Physics and Electronics. Linköping University, Faculty of Science & Engineering.ORCID iD: 0000-0001-8845-6296
2017 (English)In: Journal of Materials Chemistry A, ISSN 2050-7488, Vol. 5, no 37, p. 19619-19625Article in journal (Refereed) Published
Abstract [en]

The interest in thermogalvanic cells (TGCs) has grown because it is a candidate technology for harvesting electricity from natural and waste heat. However, the cost of TGCs has a major component due to the use of the platinum electrode. Here, we investigate new alternative electrode material based on conducting polymers, more especially poly(3,4-ethylenedioxythiophene)-Tosylate (PEDOT-Tos) together with the Ferro/Ferricyanide redox electrolyte. The power generated by the PEDOT-Tos based TGCs increases with the conducting polymer thickness/multilayer and reaches values similar to the flat platinum electrode based TGCs. The physics and chemistry behind this exciting result as well as the identification of the limiting phenomena are investigated by various electrochemical techniques. Furthermore, a preliminary study is provided for the stability of the PEDOT-Tos based TGCs.

Place, publisher, year, edition, pages
Royal Society of Chemistry, 2017. Vol. 5, no 37, p. 19619-19625
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:liu:diva-140745DOI: 10.1039/C7TA04891BISI: 000411739700007OAI: oai:DiVA.org:liu-140745DiVA, id: diva2:1140044
Note

Funding agencies: European Research Council (ERC) [307596]

Available from: 2017-09-11 Created: 2017-09-11 Last updated: 2018-11-27
In thesis
1. Conducting Polymer Electrodes for Thermogalvanic Cells
Open this publication in new window or tab >>Conducting Polymer Electrodes for Thermogalvanic Cells
2018 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

Fossil fuels are still the dominant (ca. 80%) energy source in our society. A significant fraction is used to generate electricity with a heat engine possessing an efficiency of approximately 35%. Therefore, about 65% of fossil fuel energy is wasted in heat. Other primary heat sources include solar and geothermal energies that can heat up solid and fluids up to 150oC. The growing demand and severe environmental impact of energy systems provide an impetus for effective management and harvesting solutions dealing with waste heat. A promising way to use waste heat is to directly convert thermal energy into electrical energy by thermoelectric generators (TEGs). Solid state TEGs are electronic devices that generate electrical power due to the thermo-diffusion of electronic charge carriers in the semiconductor upon application of the thermal field. However, there is another type of thermoelectric device that has been much less investigated; this is the thermogalvanic cell (TGCs). The TGC is an electrochemical device that consists of the electrolyte solution including a reversible redox couple sandwiched between two electrodes. In our study, we focus on iron-based organometallic molecules in aqueous electrolyte. A temperature difference (Δ𝑇) between the electrodes promotes a difference in the electrode potentials [Δ𝐸(𝑇)]. Since the electrolyte contains a redox couple acting like electronic shuttle between the two electrodes, power can be generated when the two electrodes are submitted to a temperature difference. The focus of this thesis is (i) to investigate the possibility to use conducting polymer electrodes for thermogalvanic cells as an alternative to platinum and carbon-based electrodes, (ii) to investigate the role of viscosity of the electrolyte in order to consider polymer electrolytes, (iii) to understand the mechanisms limiting the electrical power output in TGCs; and (iv) to understand the fundamentals of the electron transfer taking place at the interface between the polymer electrode and the redox molecule in the electrolyte. These findings provide an essential toolbox for further improvement in conducting polymer thermoglavanic cells and various other emerging electrochemical technologies such as fuel cells, redox flow battery, dye-sensitized solar cells and industrial electrochemical synthesis.

Place, publisher, year, edition, pages
Linköping: Linköping University Electronic Press, 2018. p. 93
Series
Linköping Studies in Science and Technology. Dissertations, ISSN 0345-7524 ; 1971
National Category
Energy Engineering Energy Systems Other Environmental Engineering Materials Chemistry
Identifiers
urn:nbn:se:liu:diva-152888 (URN)10.3384/diss.diva-152888 (DOI)9789176851562 (ISBN)
Public defence
2018-12-07, K3, Kåkenhus, Campus Norrköping, Norrköping, 10:00 (English)
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Available from: 2018-11-27 Created: 2018-11-27 Last updated: 2018-11-27Bibliographically approved

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