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Rapid growth of fully-inorganic flexible CaxCoO2 thin films from a ligand free aqueous precursor ink for thermoelectric applications
Indian Inst Technol, India; Gyeongsang Natl Univ, South Korea.
Gyeongsang Natl Univ, South Korea.
Gyeongsang Natl Univ, South Korea.
Indian Inst Technol, India; SN Bose Natl Ctr Basic Sci, India.
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2019 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 55, no 54, p. 7784-7787Article in journal (Refereed) Published
Abstract [en]

We demonstrate a ligand-free green chemical method for the rapid growth of nanoporous Ca0.35CoO2 thin films on sapphire and mica substrates from a water-based precursor ink, formulated by dissolving the precursor solid, composed of in situ prepared Ca2+-DMF and Co2+-DMF complexes. Mica serves as the flexible substrate as well as the sacrificial layer for the film transfer. Despite the presence of nanopores, the power factor of the flexible film Ca0.35CoO2-on-mica is above 0.50 x 10(-4) W m(-1) K-2 at around room temperature. The present technique is simple and cost-effective.

Place, publisher, year, edition, pages
ROYAL SOC CHEMISTRY , 2019. Vol. 55, no 54, p. 7784-7787
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:liu:diva-159048DOI: 10.1039/c9cc03441bISI: 000474265200010PubMedID: 31210211OAI: oai:DiVA.org:liu-159048DiVA, id: diva2:1338426
Note

Funding Agencies|Science and Engineering Research Board, the DST "GPU", Government of India [SERB/1759/2014-15]; Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education [2016R1D1A1B03931391]; Aforsk foundation [17-578]; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoping University (Faculty Grant SFO-Mat-LiU) [2009 00971]

Available from: 2019-07-22 Created: 2019-07-22 Last updated: 2019-08-20

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