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POLYFERROCENES AS MEDIATORS IN AMPEROMETRIC BIOSENSORS FOR GLUCOSE
CRANFIELD INST TECHNOL,CRANFIELD BIOTECHNOL CTR,CRANFIELD MK43 0AL,BEDS,ENGLAND; UNIV WITWATERSRAND,DEPT CHEM,JOHANNESBURG 2001,SOUTH AFRICA; .
CRANFIELD INST TECHNOL,CRANFIELD BIOTECHNOL CTR,CRANFIELD MK43 0AL,BEDS,ENGLAND; UNIV WITWATERSRAND,DEPT CHEM,JOHANNESBURG 2001,SOUTH AFRICA; .
Cranfield University, UK.ORCID-id: 0000-0002-1815-9699
CRANFIELD INST TECHNOL,CRANFIELD BIOTECHNOL CTR,CRANFIELD MK43 0AL,BEDS,ENGLAND; UNIV WITWATERSRAND,DEPT CHEM,JOHANNESBURG 2001,SOUTH AFRICA; .
1993 (engelsk)Inngår i: Analytica Chimica Acta, ISSN 0003-2670, E-ISSN 1873-4324, Vol. 281, nr 3, s. 453-459Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

This paper describes the first successful application of polymeric ferrocenes as mediators in amperometric biosensors. The results have implications for the design of stable biosensors and bioelectronic devices involving electron transfer from oxidoreductases to electrode surfaces. The behaviour of two ferrocene polymers in enzyme electrodes was explored and a distinctive pH profile was noted. It is suggested that changes in either the enzyme conformation or the polymer in response to hydrogen ion concentration may explain the difference in behaviour between monomeric and polymeric ferrocenes.

sted, utgiver, år, opplag, sider
Elsevier Science B.V., Amsterdam. , 1993. Vol. 281, nr 3, s. 453-459
Emneord [en]
AMPEROMETRY; BIOSENSORS; ENZYMATIC METHODS; ENZYME ELECTRODES; FERROCENES; GLUCOSE; GLUCOSE OXIDASE
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Identifikatorer
URN: urn:nbn:se:liu:diva-65295ISI: A1993MA13200002OAI: oai:DiVA.org:liu-65295DiVA, id: diva2:394937
Tilgjengelig fra: 2011-02-04 Laget: 2011-02-04 Sist oppdatert: 2017-12-11

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