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Vibrational Study of SOx Adsorption on Pt/SiO2
Chalmers, Dept Chem & Biol Engn, SE-41296 Gothenburg, Sweden Chalmers, Competence Ctr Catalysis, SE-41296 Gothenburg, Sweden .
Linköpings universitet, Institutionen för fysik, kemi och biologi, Tillämpad sensorvetenskap. Linköpings universitet, Tekniska högskolan.
Linköpings universitet, Institutionen för fysik, kemi och biologi, Tillämpad sensorvetenskap. Linköpings universitet, Tekniska högskolan.
Linköpings universitet, Institutionen för fysik, kemi och biologi, Kemi. Linköpings universitet, Tekniska högskolan.ORCID-id: 0000-0002-5341-2637
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2014 (engelsk)Inngår i: The Journal of Physical Chemistry C, ISSN 1932-7447, E-ISSN 1932-7455, Vol. 118, nr 51, s. 29713-29723Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The formation of ad-SOx species on Pt/SiO2 upon exposure to SO2 in concentrations ranging from 10 to 50 ppm at between 200 and 400 degrees C has been studied by in situ diffuse reflectance infrared Fourier transformed spectroscopy. In parallel, first-principles calculations have been carried out to consolidate the experimental interpretations. It was found that sulfate species form on the silica surface with a concomitant removal/rearrangement of silanol groups. Formation of ad-SOx species occurs only after SO2 oxidation to SO3 on the platinum surface. Thus, SO2 oxidation to SO3 is the first step in the SOx adsorption process, followed by spillover of SO3 to the oxide, and finally, the formation of sulfate species on the hydroxyl positions on the oxide. The sulfate formation is influenced by both temperature and SO2 concentration. Furthermore, exposure to hydrogen is shown to be sufficiently efficient as to remove ad-SOx species from the silica surface.

sted, utgiver, år, opplag, sider
American Chemical Society , 2014. Vol. 118, nr 51, s. 29713-29723
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Identifikatorer
URN: urn:nbn:se:liu:diva-114017DOI: 10.1021/jp506644wISI: 000347360200028OAI: oai:DiVA.org:liu-114017DiVA, id: diva2:786759
Merknad

Funding Agencies|Chalmers University of Technology; Swedish Energy Agency; AB Volvo; ECAPS AB; Haldor Topsoe A/S; Scania CV AB; Volvo Car Corp. AB; Wartsila Finland Oy; Swedish Research Council (VR)

Tilgjengelig fra: 2015-02-06 Laget: 2015-02-05 Sist oppdatert: 2017-12-04

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