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Fast switching polymeric electrochromics with facile processed water dispersed nanoparticles
Linköping University, Department of Physics, Chemistry and Biology, Biomolecular and Organic Electronics. Linköping University, Faculty of Science & Engineering.
Linköping University, Department of Physics, Chemistry and Biology, Surface Physics and Chemistry. Linköping University, Faculty of Science & Engineering.
Linköping University, Department of Science and Technology, Physics and Electronics. Linköping University, Faculty of Science & Engineering.ORCID iD: 0000-0001-8478-4663
Linköping University, Department of Physics, Chemistry and Biology, Surface Physics and Chemistry. Linköping University, Faculty of Science & Engineering.ORCID iD: 0000-0001-9879-3915
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2018 (English)In: Nano Energy, ISSN 2211-2855, E-ISSN 2211-3282, Vol. 47, p. 123-129Article in journal (Refereed) Published
Abstract [en]

In this work, water dispersed electrochromic polymer nanoparticles (WDENs) prepared with miniemulsion process are introduced into electrochromic polymer (ECP) electrode for the first time. The poly [2, 3-bis-(3-octyloxyphenyl) quinoxaline-5,8-diyl-alt-thiophene-2,5-diyl]) nanoparticle (NP) electrode shows much faster switching speed than the compacted electrode (e.g. 2.10 s vs. 24.15 s for coloring, 8.65 s vs. 25.95 s for bleaching @ 0.4 V; 1.30 s vs. 9.20 s coloring and 1.7 s vs. 2.90 s for bleaching @ 1.0 V). Moreover, the potentiality of WDENs for universal ECPs is demonstrated. The microelectrochemical measurement indicates much more efficient counter-ion diffusion between the electrolyte and the NP films than the compacted films, which results in much faster electrochromic switching. Besides the facile and eco-friendly processing of the WDENs, all solution and low cost fabrication of ECP NP films suggest their broad applications in commercial production of polymer electrochromic display and great potential for other polymer electrochemical electronics.

Place, publisher, year, edition, pages
ELSEVIER SCIENCE BV , 2018. Vol. 47, p. 123-129
Keywords [en]
Electrochromics; Conjugated polymer; Nanoparticles; Fast switching; Facile processing
National Category
Materials Chemistry
Identifiers
URN: urn:nbn:se:liu:diva-147786DOI: 10.1016/j.nanoen.2018.02.050ISI: 000430057000015OAI: oai:DiVA.org:liu-147786DiVA, id: diva2:1206500
Note

Funding Agencies|Swedish Research Council (VR) [621-2013-5561]; VINNMER Marie Curie from VINNOVA [2016-02840]; Goran Gustafsson Foundation for Research in Nature Sciences and Medicine

Available from: 2018-05-17 Created: 2018-05-17 Last updated: 2018-05-17

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Xing, XingZeng, QiVagin, MikhailFahlman, MatsZhang, Fengling
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