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Comparison of O-2 and H2O as oxygen source for homoepitaxial growth of beta-Ga2O3 layers by halide vapor phase epitaxy
Tokyo Univ Agr and Technol, Japan.
Tokyo Univ Agr and Technol, Japan; Novel Crystal Technol Inc, Japan.
Tokyo Univ Agr and Technol, Japan.
Tokyo Univ Agr and Technol, Japan.
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2018 (English)In: Journal of Crystal Growth, ISSN 0022-0248, E-ISSN 1873-5002, Vol. 492, p. 39-44Article in journal (Refereed) Published
Abstract [en]

Homoepitaxial growth of p-Ga2O3 layers by halide vapor phase epitaxy (HVPE) using O-2 or H2O as an oxygen source was investigated by thermodynamic analysis, and compared with measured properties after growth. The thermodynamic analysis revealed that Ga2O3 growth is expected even at 1000 C-degrees using both oxygen sources due to positive driving forces for Ga2O3 deposition. The experimental results for homoepitaxial growth on (0 0 1) beta-Ga2O3 substrates showed that the surfaces of the layers grown with H2O were smoother than those grown with O-2, although the growth rate with H2O was approximately half that with O-2. However, in the homoepitaxial layer grown using H2O, incorporation of Si impurities with a concentration almost equal to the effective donor concentration (2 x 10(16)cm (3)) was confirmed, which was caused by decomposition of the quartz glass reactor due to the presence of hydrogen in the system. (C) 2018 Elsevier B.V. All rights reserved.

Place, publisher, year, edition, pages
ELSEVIER SCIENCE BV , 2018. Vol. 492, p. 39-44
Keywords [en]
Thermodynamic analysis; Halide vapor phase epitaxy; Oxides; Gallium compounds; Semiconducting III-VI materials
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:liu:diva-148365DOI: 10.1016/j.jcrysgro.2018.04.009ISI: 000432747200008OAI: oai:DiVA.org:liu-148365DiVA, id: diva2:1219063
Note

Funding Agencies|Council for Science, Technology and Innovation (CSTI), Cross-ministerial Strategic Innovation Promotion Program (SIP), "Next-generation power electronics" (funding agency: NEDO); Japan Society for the Promotion of Science [16H06417, 16K04944]

Available from: 2018-06-15 Created: 2018-06-15 Last updated: 2018-06-15

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