New copolymers with fluorinated and non-fluorinated benzothiadiazole units for efficient single layer near infra-red photodiodes with fast time responseShow others and affiliations
2018 (English)In: Synthetic metals, ISSN 0379-6779, E-ISSN 1879-3290, Vol. 243, p. 67-74Article in journal (Refereed) Published
Abstract [en]
We describe the synthesis and photodetecting properties of new, low band-gap copolymers: P1 with 5,6-difluoro-2,1,3-benzothiadiazole and P2 with 2,1,3-benzothiadiazole, both containing diketopyrrolopyrrole acceptor units. These compounds have been used for fabrication of single layer, solution processed photodetectors. For this purpose, two blends with fullerene derivative (6,6)-phenyl-C61-butyric acid methyl ester ([60]PCBM): P1: [60]PCBM and P2:[60]PCBM, were prepared and applied as active layers in bulk-heterojunction photodiodes. For near infrared light (810 nm), these photodetectors, in spite of single layer structure, display competitive performance, showing specific detectivity up to 5.10(11) Jones, responsivity up to 0.3 A/W and rise and fall times of the transient signals below 10 mu s.
Place, publisher, year, edition, pages
ELSEVIER SCIENCE SA , 2018. Vol. 243, p. 67-74
Keywords [en]
Organic electronics; Donor-acceptor copolymers; Polymer photodetectors; Near-infrared photodetectors; Bulk heterojunction; Organic photodiodes
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:liu:diva-150212DOI: 10.1016/j.synthmet.2018.06.005ISI: 000439402300009OAI: oai:DiVA.org:liu-150212DiVA, id: diva2:1241052
Note
Funding Agencies|Russian Foundation for Basic Research (RFBR) [16-29-06337 ofi_m]; Russian Federal Agency for Scientific Organizations [20089-2014-0036]; National Science Centre (Poland) [UMO-2013/09/B/ST5/03521]; Swedish Foundation for Strategic Research [SE13-0060]
2018-08-222018-08-222018-08-22