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Molecular and Energetic Order Dominate the Photocurrent Generation Process in Organic Solar Cells with Small Energetic Offsets
Xi An Jiao Tong Univ, Peoples R China.
Linköping University, Department of Physics, Chemistry and Biology, Biomolecular and Organic Electronics. Linköping University, Faculty of Science & Engineering.
Washington State Univ, WA 99164 USA.
Xi An Jiao Tong Univ, Peoples R China.
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2020 (English)In: ACS Energy Letters, E-ISSN 2380-8195, Vol. 5, no 2, p. 589-596Article in journal (Refereed) Published
Abstract [en]

Minimizing the energetic offset between the donor (D) and acceptor (A) in organic solar cells (OSCs) is pivotal for reducing the charge-transfer (CT) loss and improving the open-circuit voltage (V-oc). This nevertheless leads to a topic of debate regarding the driving force for the charge separation in OSCs with small energetic offsets. The molecular packing geometries in the active layer determine the energetic levels and trap density, but their relationship with the driving force is seldom considered. Limited by the complicated demixing morphology and inaccurate measurements of energy levels in the prototypical bulk-heterojunction (BHJ) devices, we thereby demonstrate a concise and robust planar-heterojunction model of PM7/N2200 to investigate the origin of driving force for charge generation. It is surprising to note that the device with smaller energy offset shows higher efficiency. Further analysis reveals that a bilayer device with short-range packing PM7 exhibits smaller energetic offsets along with fewer morphological defects and traps compared to its long-range packing counterparts. This molecular packing characteristic diminishes the energetic disorder at the D/A interfaces and inhibits the trap-assisted charge recombination, contributing to the increased short-circuit current (J(SC)) and V-OC. Our results suggest that the energetic offset actually has limited influence on charge separation, while the synergetic control of molecular and energetic order is vital to the photocurrent generation and energy loss reduction in OSCs.

Place, publisher, year, edition, pages
AMER CHEMICAL SOC , 2020. Vol. 5, no 2, p. 589-596
National Category
Condensed Matter Physics
Identifiers
URN: urn:nbn:se:liu:diva-164673DOI: 10.1021/acsenergylett.0c00029ISI: 000514258200030OAI: oai:DiVA.org:liu-164673DiVA, id: diva2:1417559
Note

Funding Agencies|Ministry of Science and Technology [2016YFA0200700]; NSFCNational Natural Science Foundation of China [21704082, 21875182]; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2017M623162]; 111 project 2.0 [BP2018008]; Office of Science, Office of Basic Energy Sciences, of the U.S. Department of EnergyUnited States Department of Energy (DOE) [DE-AC02-05CH11231]

Available from: 2020-03-29 Created: 2020-03-29 Last updated: 2020-12-15

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