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Facile preparation of sulfonated biochar for highly efficient removal of toxic Pb(II) and Cd(II) from wastewater
Tongji Univ, Peoples R China.
Linköping University, Department of Physics, Chemistry and Biology, Molecular Surface Physics and Nano Science. Linköping University, Faculty of Science & Engineering. Shanghai Univ, Peoples R China.
Chongqing Res Acad Environm Sci, Peoples R China.
Tongji Univ, Peoples R China.
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2021 (English)In: Science of the Total Environment, ISSN 0048-9697, E-ISSN 1879-1026, Vol. 750, article id 141545Article in journal (Refereed) Published
Abstract [en]

Biochar is deemed as the ideal material for the effective removal of heavy metals in wastewater treatment. Herein, we developed a facile one-step solvothermal method for the preparation of sulfonated biochar (SBC) from Axonopus compressus under a low-temperature condition. FTIR and XPS analysis demonstrate that plenty of -OH, -COOH and -SO3H moieties are generated on the surface of SBC during the sulfonation process. Due to high electronegativity and strong complexation of these moieties, SBC can rapidly adsorb Pb(II) and Cd(II) with capacities of 191.07 and 85.76 mg/g respectively within 5 min. SBC can be reused for 5 cycles with a negligible loss of adsorption capacity. In addition, different biomass-based biochars are prepared under the identical experimental conditions, and they are successfully applied in the treatments of Pb(II) and Cd(II). The satisfying results indicate that one-step low-temperature sulfonation could be a universalmethod, and various types of biomass waste could be the abundant, effective, economical material source for the treatment of environmental heavy metal pollution in future. (C) 2020 Elsevier B.V. All rights reserved.

Place, publisher, year, edition, pages
ELSEVIER , 2021. Vol. 750, article id 141545
Keywords [en]
Biochar; Low-temperature; Pb(II)/Cd(II); Sulfonation; Ultra-fast adsorption
National Category
Other Environmental Engineering
Identifiers
URN: urn:nbn:se:liu:diva-172087DOI: 10.1016/j.scitotenv.2020.141545ISI: 000585694600053PubMedID: 33182166OAI: oai:DiVA.org:liu-172087DiVA, id: diva2:1512716
Note

Funding Agencies|Key Program for International S&T Cooperation Projects of China [2016YFE0123800]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21577098]; Natural Science Foundation of ShanghaiNatural Science Foundation of Shanghai [17ZR1410500]; STINT Joint China-Sweden Mobility Project Program [CH2017-7243]

Available from: 2020-12-28 Created: 2020-12-28 Last updated: 2020-12-28

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