Ultrathin Single-Crystalline 2D Perovskite Photoconductor for High-Performance Narrowband and Wide Linear Dynamic Range PhotodetectionShow others and affiliations
(English)In: Small, ISSN 1613-6810, E-ISSN 1613-6829, article id 2005626Article in journal (Refereed) Epub ahead of print
Abstract [en]
For next-generation Internet-of-Everything applications, for example, artificial-neural-network image sensors, artificial retina, visible light communication, on-chip light interconnection, and flexible devices, etc., high-performance microscale photodetectors are in urgent demands. 2D material (2DM) photodetectors have been researched and demonstrated impressive performances. However, they have not met the demands in filterless narrowband photoresponse, wide linear dynamic range (LDR), ultralow dark current, and large on/off ratio, which are key performances for these applications. 2D Ruddlesden-Popper perovskites (2D-RPPs) are recently highlighted photovoltaic and optoelectronic materials. Embedding ultrathin 2D-RPPs into 2DM photodetectors holds potentials to improve these performances. Herein, a single-crystalline ultrathin (PEA)(2)PbI4 is integrated into a vertical-stacked graphene-(PEA)(2)PbI4-graphene micro photoconductor (V-PEPI-PC). V-PEPI-PC exhibits narrowband photoresponses at 517 nm with a full-width-at-half-maximum of 15 nm and a wide LDR of 122 dB. Due to the multiple quantum wells in (PEA)(2)PbI4, V-PEPI-PC demonstrates an ultralow dark current of 1.1 x 10(-14) A (44 pA mm(-2)), a high specific detectivity of 1.2 x 10(13) Jones, and a high on/off ratio of 1.6 x 10(6). Owing to the short vertical channel, V-PEPI-PC shows a fast response rise time of 486 mu s. Therefore, the vertical-stacked photodetectors based on hybrid 2D-RPPs and 2DMs may have great potentials in future optoelectronics.
Place, publisher, year, edition, pages
WILEY-V C H VERLAG GMBH. article id 2005626
Keywords [en]
2D materials; 2D perovskites; linear dynamic range; narrowband; photodetectors
National Category
Biomedical Laboratory Science/Technology
Identifiers
URN: urn:nbn:se:liu:diva-172244DOI: 10.1002/smll.202005626ISI: 000594736600001PubMedID: 33283445OAI: oai:DiVA.org:liu-172244DiVA, id: diva2:1512949
Note
Funding Agencies|China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2019M653016]; Science, Technology and Innovation Commission of Shenzhen Municipality [JCYJ20190808142603561]; 1000 Talents Program for Young Scientists of China, Shenzhen Peacock Plan [KQTD2016053112042971]; Educational Commission of Guangdong Province [2016KCXTD006]
2020-12-282020-12-282020-12-28