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Electron irradiation induced modifications of Ti(1-x)AlxN coatings and related buffer layers on steel substrates
Fraunhofer Inst Surface Engn & Thin Films IST, Germany.
Linköping University, Department of Physics, Chemistry and Biology, Thin Film Physics. Linköping University, Faculty of Science & Engineering.
Fraunhofer Inst Surface Engn & Thin Films IST, Germany.
Fraunhofer Inst Surface Engn & Thin Films IST, Germany.
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2021 (English)In: Vacuum, ISSN 0042-207X, E-ISSN 1879-2715, Vol. 185, article id 110028Article in journal (Refereed) Published
Abstract [en]

Ti(1-x )AlxN hard coatings were prepared by reactive magnetron sputtering onto steel substrates (51CrV4 - 1.8159) and subsequently exposed for a short-time (similar to 1 s) to high-flux electron beam (EB) treatment. Morphology, composition and the structure of as-deposited and EB treated coatings were investigated using transmission electron microscopy (TEM), secondary ion mass spectroscopy (SIMS) and X-ray diffraction (XRD). It was found that the EB treatment had only a minor influence on the morphology and crystallinity of the Ti(1-x)AlxN phase, however, the stress-free lattice parameter and partly the compressive stress in the coatings were clearly reduced by the treatment. On the other hand, major changes of composition profiles and structure were observed in the metallic buffer layer between substrate and Ti(1-x)AlxN. The observed modifications in the coating-substrate system are explained by rapid heat up and radiation damage due to the fast electron exposure.

Place, publisher, year, edition, pages
Elsevier, 2021. Vol. 185, article id 110028
Keywords [en]
Nitride hard coatings; Reactive magnetron sputtering; Electron beam treatment; Stress relaxation; Electron-surface interaction
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:liu:diva-174105DOI: 10.1016/j.vacuum.2020.110028ISI: 000618237200003Scopus ID: 2-s2.0-85098879557OAI: oai:DiVA.org:liu-174105DiVA, id: diva2:1537474
Note

Funding Agencies|Deutsche Forschungsgemeinschaft (DFG)German Research Foundation (DFG) [BI418/22-1, BR2178/16-1]

Available from: 2021-03-15 Created: 2021-03-15 Last updated: 2021-03-22Bibliographically approved

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Hultman, Lars

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