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Investigation of halide vapor phase epitaxy of In2O3 on sapphire (0001) substrates
Tokyo Univ Agr & Technol, Japan.
Sophia Univ, Japan.
Tokyo Univ Agr & Technol, Japan.
Linköping University, Department of Physics, Chemistry and Biology, Semiconductor Materials. Linköping University, Faculty of Science & Engineering.
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2021 (English)In: Journal of Crystal Growth, ISSN 0022-0248, E-ISSN 1873-5002, Vol. 563, article id 126111Article in journal (Refereed) Published
Abstract [en]

The effect of the growth conditions on halide vapor phase epitaxy of In2O3 on sapphire (0 0 0 1) substrates was investigated. Only the most thermally stable phase c-In2O3 grows at growth temperatures of 400 to 1000 degrees C. The growth rate increased as the growth temperature increased up to 700 degrees C, and layers with rough surfaces and a preferred (100) orientation were grown. Above 700 degrees C, the growth rate became constant, the preferential orientation changed to (111), and layers with smooth surfaces were grown. At 1000 degrees C, the volume fraction of the (111)-oriented domains in the grown layer reached 99.0%, although there were in-plane twins rotated by 180 degrees. The growth rate also increased as the input partial pressure of the InCl or O-2 source gas was increased, and a high growth rate exceeding 10 mu m/h was found. The layer grown at 1000 degrees C was of high purity and incorporated no impurities other than Cl. Optical transmission measurements of this layer showed high optical transmittance at energies below the optical gap of 3.47 eV.

Place, publisher, year, edition, pages
ELSEVIER , 2021. Vol. 563, article id 126111
Keywords [en]
Crystal structure; Halide vapor phase epitaxy; Oxides; Semiconducting III-VI materials; Semiconducting indium compounds
National Category
Condensed Matter Physics
Identifiers
URN: urn:nbn:se:liu:diva-175585DOI: 10.1016/j.jcrysgro.2021.126111ISI: 000637749200003OAI: oai:DiVA.org:liu-175585DiVA, id: diva2:1553593
Note

Funding Agencies|Japan Society for the Promotion of ScienceMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of Science [16H06417, 16K04944]; Institute of Global Innovation Research, Tokyo University of Agriculture and Technology

Available from: 2021-05-10 Created: 2021-05-10 Last updated: 2021-05-10

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