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Accelerated aging of all-inorganic, interface-stabilized perovskite solar cells
Princeton Univ, NJ 08544 USA.
Princeton Univ, NJ 08544 USA; Princeton Univ, NJ 08544 USA.
Princeton Univ, NJ 08544 USA.
Linköping University, Department of Physics, Chemistry and Biology, Electronic and photonic materials. Linköping University, Faculty of Science & Engineering.ORCID iD: 0000-0002-3630-0414
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2022 (English)In: Science, ISSN 0036-8075, E-ISSN 1095-9203, Vol. 377, no 6603, p. 307-310Article in journal (Refereed) Published
Abstract [en]

To understand degradation routes and improve the stability of perovskite solar cells (PSCs), accelerated aging tests are needed. Here, we use elevated temperatures (up to 110 degrees C) to quantify the accelerated degradation of encapsulated CsPbI3 PSCs under constant illumination. Incorporating a two-dimensional (2D) Cs2PbI2Cl2 capping layer between the perovskite active layer and hole-transport layer stabilizes the interface while increasing power conversion efficiency of the all-inorganic PSCs from 14.9 to 17.4%. Devices with this 2D capping layer did not degrade at 35 degrees C and required >= 2100 hours at 110 degrees C under constant illumination to degrade by 20% of their initial efficiency. Degradation acceleration factors based on the observed Arrhenius temperature dependence predict intrinsic lifetimes of 51,000 +/- 7000 hours (>5 years) operating continuously at 35 degrees C.

Place, publisher, year, edition, pages
AMER ASSOC ADVANCEMENT SCIENCE , 2022. Vol. 377, no 6603, p. 307-310
National Category
Materials Chemistry
Identifiers
URN: urn:nbn:se:liu:diva-187381DOI: 10.1126/science.abn5679ISI: 000830834200034PubMedID: 35709247OAI: oai:DiVA.org:liu-187381DiVA, id: diva2:1688918
Note

Funding Agencies|US DOE Office of Science Facilities, at Brookhaven National Laboratory [DE-SC0012704]; Princeton Center for Complex Materials (PCCM), a National Science Foundation (NSF)-MRSEC program [DMR-2011750]; National Science Foundation [DMR-1627453, CMMI-1824674]; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoping University (Faculty Grant SFO-Mat-LiU) [2009-00971]; Julis Romo Rabinowitz Graduate Fellowship; Arnold and Mabel Beckman Foundation

Available from: 2022-08-19 Created: 2022-08-19 Last updated: 2024-02-21

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