Source and migration of short-chain chlorinated paraffins in the coastal East China Sea using multiproxies of marine organic geochemistryShow others and affiliations
2013 (English)In: Environmental Science and Technology, ISSN 0013-936X, E-ISSN 1520-5851, Vol. 47, no 10, p. 5013-5022Article in journal (Refereed) Published
Abstract [en]
Multiple proxies of terrestrial organic matters (TOM) were introduced to study the migration behaviors of short-chain chlorinated paraffins (SCCPs) in the coastal East China Sea (ECS). The contents of SCCPs in the surface sediment collected from Changjiang (Yangtze) River Delta (CRD) and along the Zhejiang-Fujian coastline ranged from 9.0 to 37.2 ng/g (dry weight, d.w.), displaying a "band-style" distribution trend. Spatial distribution patterns of SCCP congeners presented an increasing trend seaward and southward along the coastline for shorter carbon length (C₁₀ + C₁₁) and lower chlorinated (Cl₅ + Cl₆ + Cl₇) congeners, suggesting a spreading tendency seaward and southward from the CRD and the north of the inner shelf. The significant relationship between ΣSCCPs and total organic carbons (TOC) (r(2) = 0.402, p < 0.05) indicated that the migration of SCCPs in sediments was markedly affected by TOC. The spatial patterns of the TOM proxies of TOC δ(13)C, the contents of ΣC₂₇ + C₂₉ + C₃₁ n-alkanes, terrestrial marine biomarker ratio (TMBR), and terrestrial TOC (T-TOC) were all similar to that of ΣSCCPs. Linear relationships between SCCP contents and both the contents of ΣC₂₇ + C₂₉ + C₃₁ n-alkanes (r(2) = 0.537, p < 0.05) and T-TOC (r(2) = 0.495, p < 0.05) were also observed. The consistence demonstrated that a major portion of sedimentary SCCPs in the coastal ECS should be from the river input of Changjiang River and deposited in the CRD and along the inner shelf of the ECS, but only a minor fraction was transported to the offshore areas.
Place, publisher, year, edition, pages
American Chemical Society (ACS) , 2013. Vol. 47, no 10, p. 5013-5022
Keywords [en]
China; Chlorine; Paraffin; Quality Control; Seawater; Water Pollutants, Chemical
National Category
Environmental Sciences
Identifiers
URN: urn:nbn:se:liu:diva-193868DOI: 10.1021/es304899jISI: 000319708600008PubMedID: 23611620Scopus ID: 2-s2.0-84878249450OAI: oai:DiVA.org:liu-193868DiVA, id: diva2:1757334
Note
Sponsors:
National Natural Science Foundation Grant no:s 21007062 21007078 41020164005
SKLECE Open Fund KF2009-21
Young Teachers Special Fund
Ocean University of China Grant no: 201013018
SOA Open Fund Grant no: MESE-2011-07
2023-05-162023-05-162023-05-29