Summer-winter concentrations and gas-particle partitioning of short chain chlorinated paraffins in the atmosphere of an urban settingShow others and affiliations
2012 (English)In: Environmental Pollution, ISSN 0269-7491, E-ISSN 1873-6424, Vol. 171, p. 38-45Article in journal (Refereed) Published
Abstract [en]
Short chain chlorinated paraffins (SCCPs) are semi-volatile chemicals that are considered persistent in the environment, potential toxic and subject to long-range transport. This study investigates the concentrations and gas-particle partitioning of SCCPs at an urban site in Beijing during summer and wintertime. The total atmospheric SCCP levels ranged 1.9-33.0 ng/m(3) during wintertime. Significantly higher levels were found during the summer (range 112-332 ng/m(3)). The average fraction of total SCCPs in the particle phase (ϕ) was 0.67 during wintertime but decreased significantly during the summer (ϕ = 0.06). The ten and eleven carbon chain homologues with five to eight chlorine atoms were the predominant SCCP formula groups in air. Significant linear correlations were found between the gas-particle partition coefficients and the predicted subcooled vapor pressures and octanol-air partition coefficients. The gas-particle partitioning of SCCPs was further investigated and compared with both the Junge-Pankow adsorption and K(oa)-based absorption models.
Place, publisher, year, edition, pages
Elsevier , 2012. Vol. 171, p. 38-45
Keywords [en]
Short chain chlorinated paraffins, Polychlorinated n-alkanes, Atmosphere, Air, Gas-particle partitioning
National Category
Environmental Sciences
Identifiers
URN: urn:nbn:se:liu:diva-193832DOI: 10.1016/j.envpol.2012.07.025ISI: 000310092800006PubMedID: 22868345Scopus ID: 2-s2.0-84864516050OAI: oai:DiVA.org:liu-193832DiVA, id: diva2:1757375
Note
Sponsors:
National High-Tech R&D Program of China Grant(s): 2010AA065102
National Natural Science Foundation of China Grant(s): 21007085 20890111
Chinese Academy of Sciences Grant(s): KZCX2-YW-QN409
2023-05-162023-05-162023-05-29