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Efficient Monolithic Perovskite/Silicon Tandem Photovoltaics
Zhejiang Univ, Peoples R China; Zhejiang Univ, Peoples R China; Zhejiang Univ, Peoples R China.
Linköping University, Department of Physics, Chemistry and Biology, Electronic and photonic materials. Linköping University, Faculty of Science & Engineering.
Linköping University, Department of Physics, Chemistry and Biology, Electronic and photonic materials. Linköping University, Faculty of Science & Engineering.ORCID iD: 0000-0002-2582-1740
Zhejiang Univ, Peoples R China; Zhejiang Univ, Peoples R China; Zhejiang Univ, Peoples R China.
2024 (English)In: Energy & Environmental Materials, E-ISSN 2575-0356, Vol. 7, no 3, article id e12639Article, review/survey (Refereed) Published
Abstract [en]

Tunable bandgaps make halide perovskites promising candidates for developing tandem solar cells (TSCs), a strategy to break the radiative limit of 33.7% for single-junction solar cells. Combining perovskites with market-dominant crystalline silicon (c-Si) is particularly attractive; simple estimates based on the bandgap matching indicate that the efficiency limit in such tandem device is as high as 46%. However, state-of-the-art perovskite/c-Si TSCs only achieve an efficiency of similar to 32.5%, implying significant challenges and also rich opportunities. In this review, we start with the operating mechanism and efficiency limit of TSCs, followed by systematical discussions on wide-bandgap perovskite front cells, interface selective contacts, and electrical interconnection layer, as well as photon management for highly efficient perovskite/c-Si TSCs. We highlight the challenges in this field and provide our understanding of future research directions toward highly efficient and stable large-scale wide-bandgap perovskite front cells for the commercialization of perovskite/c-Si TSCs.

Place, publisher, year, edition, pages
WILEY , 2024. Vol. 7, no 3, article id e12639
Keywords [en]
2-terminal; electrical interconnection; perovskite; silicon tandem photovoltaics; photon management; wide-bandgap perovskites
National Category
Energy Systems
Identifiers
URN: urn:nbn:se:liu:diva-196809DOI: 10.1002/eem2.12639ISI: 001010188100001OAI: oai:DiVA.org:liu-196809DiVA, id: diva2:1790829
Note

Funding Agencies|ZJU-Hangzhou Global Scientific and Technological Innovation Center [02170000-K02013017]; National Natural Science Foundation of China [61721005]

Available from: 2023-08-23 Created: 2023-08-23 Last updated: 2024-09-24Bibliographically approved

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Gao, Feng

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