High-pressure synthesis of dysprosium carbidesShow others and affiliations
2023 (English)In: Frontiers in Chemistry, E-ISSN 2296-2646, Vol. 11, article id 1210081Article in journal (Refereed) Published
Abstract [en]
Chemical reactions between dysprosium and carbon were studied in laser-heated diamond anvil cells at pressures of 19, 55, and 58 GPa and temperatures of similar to 2500 K. In situ single-crystal synchrotron X-ray diffraction analysis of the reaction products revealed the formation of novel dysprosium carbides, Dy4C3 and Dy3C2, and dysprosium sesquicarbide Dy2C3 previously known only at ambient conditions. The structure of Dy4C3 was found to be closely related to that of dysprosium sesquicarbide Dy2C3 with the Pu2C3-type structure. Ab initio calculations reproduce well crystal structures of all synthesized phases and predict their compressional behavior in agreement with our experimental data. Our work gives evidence that high-pressure synthesis conditions enrich the chemistry of rare earth metal carbides.
Place, publisher, year, edition, pages
FRONTIERS MEDIA SA , 2023. Vol. 11, article id 1210081
Keywords [en]
high-pressure; diamond anvil cell; rare-earth carbides; carbides; rare-earth elements; lanthanides carbides; dysprosium carbide
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:liu:diva-198878DOI: 10.3389/fchem.2023.1210081ISI: 001079510900001PubMedID: 37383952OAI: oai:DiVA.org:liu-198878DiVA, id: diva2:1809212
Note
Funding Agencies|Federal Ministry of Education and Research, Germany (BMBF) [05K19WC1]; Deutsche Forschungsgemeinschaft (DFG) [DU 954-11/1, DU 393-9/2, DU 393-13/1]; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoping University (Faculty Grant SFO-Mat-LiU) [2009 00971]; UKRI Future Leaders Fellowship [MR/V025724/1]
2023-11-022023-11-022024-04-22