liu.seSearch for publications in DiVA
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
High-pressure synthesis of dysprosium carbides
Univ Bayreuth, Germany; Univ Bayreuth, Germany.
Univ Bayreuth, Germany.
Univ Bayreuth, Germany; Univ Bayreuth, Germany.
Univ Bayreuth, Germany; Shandong Univ, Peoples R China.
Show others and affiliations
2023 (English)In: Frontiers in Chemistry, E-ISSN 2296-2646, Vol. 11, article id 1210081Article in journal (Refereed) Published
Abstract [en]

Chemical reactions between dysprosium and carbon were studied in laser-heated diamond anvil cells at pressures of 19, 55, and 58 GPa and temperatures of similar to 2500 K. In situ single-crystal synchrotron X-ray diffraction analysis of the reaction products revealed the formation of novel dysprosium carbides, Dy4C3 and Dy3C2, and dysprosium sesquicarbide Dy2C3 previously known only at ambient conditions. The structure of Dy4C3 was found to be closely related to that of dysprosium sesquicarbide Dy2C3 with the Pu2C3-type structure. Ab initio calculations reproduce well crystal structures of all synthesized phases and predict their compressional behavior in agreement with our experimental data. Our work gives evidence that high-pressure synthesis conditions enrich the chemistry of rare earth metal carbides.

Place, publisher, year, edition, pages
FRONTIERS MEDIA SA , 2023. Vol. 11, article id 1210081
Keywords [en]
high-pressure; diamond anvil cell; rare-earth carbides; carbides; rare-earth elements; lanthanides carbides; dysprosium carbide
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:liu:diva-198878DOI: 10.3389/fchem.2023.1210081ISI: 001079510900001PubMedID: 37383952OAI: oai:DiVA.org:liu-198878DiVA, id: diva2:1809212
Note

Funding Agencies|Federal Ministry of Education and Research, Germany (BMBF) [05K19WC1]; Deutsche Forschungsgemeinschaft (DFG) [DU 954-11/1, DU 393-9/2, DU 393-13/1]; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoping University (Faculty Grant SFO-Mat-LiU) [2009 00971]; UKRI Future Leaders Fellowship [MR/V025724/1]

Available from: 2023-11-02 Created: 2023-11-02 Last updated: 2024-04-22

Open Access in DiVA

fulltext(2313 kB)156 downloads
File information
File name FULLTEXT01.pdfFile size 2313 kBChecksum SHA-512
36b99bc3a0bc20fff40ce6a95007130e6bea68abbaee4c944672d6fdf564361c40f1de2c402ba55ac3943caa3bd527377a49cbde475bc54d1fd19e59bf382bd1
Type fulltextMimetype application/pdf

Other links

Publisher's full textPubMed

Search in DiVA

By author/editor
Trybel, FlorianDoubrovinckaia, Natalia
By organisation
Theoretical PhysicsFaculty of Science & Engineering
In the same journal
Frontiers in Chemistry
Inorganic Chemistry

Search outside of DiVA

GoogleGoogle Scholar
Total: 157 downloads
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

doi
pubmed
urn-nbn

Altmetric score

doi
pubmed
urn-nbn
Total: 242 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf