liu.seSearch for publications in DiVA
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Kinetically Controlled Synthesis of Quasi-Square CsPbI3 Nanoplatelets with Excellent Stability
Linköping University, Department of Physics, Chemistry and Biology, Electronic and photonic materials. Linköping University, Faculty of Science & Engineering.ORCID iD: 0000-0002-3161-6743
Linköping University, Department of Physics, Chemistry and Biology, Electronic and photonic materials. Linköping University, Faculty of Science & Engineering.
Linköping University, Department of Physics, Chemistry and Biology, Thin Film Physics. Linköping University, Faculty of Science & Engineering.
Linköping University, Department of Physics, Chemistry and Biology, Molecular Surface Physics and Nano Science. Linköping University, Faculty of Science & Engineering.ORCID iD: 0000-0001-9905-0881
Show others and affiliations
2024 (English)In: Small, ISSN 1613-6810, E-ISSN 1613-6829, Vol. 20, no 15, article id 2306360Article in journal (Refereed) Published
Abstract [en]

Nanoplatelets (NPLs) share excellent luminescent properties with their symmetric quantum dots counterparts and entail special characters benefiting from the shape, like the thickness-dependent bandgap and anisotropic luminescence. However, perovskite NPLs, especially those based on iodide, suffer from poor spectral and phase stability. Here, stable CsPbI3 NPLs obtained by accelerating the crystallization process in ambient-condition synthesis are reported. By this kinetic control, the rectangular NPLs into quasi-square NPLs are tuned, where enlarged width endows the NPLs with a lower surface-area-to-volume ratio (S/V ratio), leading to lower surficial energy and thus improved endurance against NPL fusion (cause for spectral shift or phase transformation). The accelerated crystallization, denoting the fast nucleation and short period of growth in this report, is enabled by preparing a precursor with complete transformation of PbI2 into intermediates (PbI3-), through an additional iodide supplier (e.g., zinc iodide). The excellent color stability of the materials remains in the light-emitting diodes under various bias stresses.

Place, publisher, year, edition, pages
WILEY-V C H VERLAG GMBH , 2024. Vol. 20, no 15, article id 2306360
Keywords [en]
accelerated crystallization; phase stability; precursor engineering; spectral stability; square perovskite nanoplatelets
National Category
Materials Chemistry
Identifiers
URN: urn:nbn:se:liu:diva-199538DOI: 10.1002/smll.202306360ISI: 001109848900001PubMedID: 38010121OAI: oai:DiVA.org:liu-199538DiVA, id: diva2:1818444
Note

Funding Agencies|National Research Infrastructure for Advanced Electron Microscopy (ARTEMI); Swedish Energy Agency [P2022-00394]; Swedish Government Strategic Research Area in Materials Science on Functional Materials at Linkoeping University [2009-00971]

Available from: 2023-12-11 Created: 2023-12-11 Last updated: 2024-10-22Bibliographically approved

Open Access in DiVA

fulltext(2435 kB)15 downloads
File information
File name FULLTEXT01.pdfFile size 2435 kBChecksum SHA-512
47171b2b8f25397d6311c49c7e76ed15e796e0fc954b965f679b815003711e72ee6fc59d6c672fa509b127490c72e637a4e25ef6ac5a81f89352d9681f305c90
Type fulltextMimetype application/pdf

Other links

Publisher's full textPubMed

Authority records

Hu, Zhang-JunZhang, RuiLiu, XianjieLiu, XiaokeGao, Feng

Search in DiVA

By author/editor
Chen, MengyunZhang, TiankaiElsukova, AnnaHu, Zhang-JunZhang, RuiWang, YonghongLiu, XianjieLiu, XiaokeGao, Feng
By organisation
Electronic and photonic materialsFaculty of Science & EngineeringThin Film PhysicsMolecular Surface Physics and Nano ScienceLaboratory of Organic Electronics
In the same journal
Small
Materials Chemistry

Search outside of DiVA

GoogleGoogle Scholar
Total: 15 downloads
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

doi
pubmed
urn-nbn

Altmetric score

doi
pubmed
urn-nbn
Total: 151 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf