Competition between decay and dissociation of core-excited carbonyl sulfide studied by x-ray scattering
1999 (English)In: Physical Review A. Atomic, Molecular, and Optical Physics, ISSN 1050-2947, E-ISSN 1094-1622, Vol. 59, 4281-4287 p.Article in journal (Refereed) Published
We show evidence of dissociation during resonant inelastic soft x-ray scattering. Carbon and oxygen K-shell and sulfur L-shell resonant and nonresonant x-ray emission spectra were measured using monochromatic synchrotron radiation for excitation and ionization. After sulfur L2,3→π*, σ* excitation, atomic lines are observed in the emission spectra as a consequence of competition between de-excitation and dissociation. In contrast the carbon and oxygen spectra show weaker line-shape variations and no atomic lines. The spectra are compared to results from ab initio calculations. The discussion of the dissociation paths is based on calculated potential energy surfaces and atomic transition energies.
Place, publisher, year, edition, pages
1999. Vol. 59, 4281-4287 p.
IdentifiersURN: urn:nbn:se:liu:diva-17470DOI: 10.1103/PhysRevA.59.4281OAI: oai:DiVA.org:liu-17470DiVA: diva2:209606
Original Publication: Martin Magnuson, J. Guo, C. Såthe, J.-E. Rubensson, J. Nordgren, P. Glans, L. Yang, P. Sałek and H. Ågren, Competition between decay and dissociation of core-excited carbonyl sulfide studied by x-ray scattering, 1999, Physical Review A. Atomic, Molecular, and Optical Physics, (59), 4281-4287. http://dx.doi.org/10.1103/PhysRevA.59.4281 Copyright: American Physical Society http://www.aps.org/2009-06-082009-03-252013-10-02Bibliographically approved