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Lithium-induced dimer reconstructions on Si(001) studied by photoelectron spectroscopy and band-structure calculations
Linköping University, Department of Physics, Chemistry and Biology, Surface and Semiconductor Physics. Linköping University, The Institute of Technology. (Yt- och Halvledarfysik, Surface and Semiconductor Physics)
Graduate School of Advanced Integrated Science Chiba University, Japan.
Linköping University, Department of Physics, Chemistry and Biology, Surface and Semiconductor Physics. Linköping University, The Institute of Technology. (Yt- och Halvledarfysik, Surface and Semiconductor Physics)
2007 (English)In: Physical Review B Condensed Matter, ISSN 0163-1829, E-ISSN 1095-3795, Vol. 75, no 20, 205416- p.Article in journal (Refereed) Published
Abstract [en]

The electronic and atomic structure of Si(001) with 0.5 and 1 ML of lithium have been studied experimentally using angle resolved ultraviolet photoelectron spectroscopy, Si 2p core level spectroscopy, and low energy electron diffraction. Experimental surface state dispersions are compared with recent theoretical results in the literature and with results from additional density functional theory calculations. Four adsorption configurations for the 0.5 ML 2×2 surface and three configurations for the 1 ML 2×1 surface are compared. Fittings of Si 2p core level data support the alternation of strongly and weakly buckled Si dimers of the 2×2 models and symmetric Si dimers of the 2×1 models based on the relative intensities of the surface components. As a tool to differentiate between the different 2×2 and 2×1 models surface state dispersions are used since they are sensitive to the positions of the Li adatoms.

Place, publisher, year, edition, pages
2007. Vol. 75, no 20, 205416- p.
National Category
Natural Sciences
URN: urn:nbn:se:liu:diva-39513DOI: 10.1103/PhysRevB.75.205416ISI: 000246890900117Local ID: 49105OAI: diva2:260362
Available from: 2013-03-26 Created: 2009-10-10 Last updated: 2013-03-26Bibliographically approved
In thesis
1. Atomic and Electronic Structures of Clean and Metal Adsorbed Si and Ge Surfaces: An Experimental and Theoretical Study
Open this publication in new window or tab >>Atomic and Electronic Structures of Clean and Metal Adsorbed Si and Ge Surfaces: An Experimental and Theoretical Study
2010 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

In this work, a selection of unresolved topics regarding the electronic and atomic structures of Si and Ge surfaces, both clean ones and those modified by metal adsorbates, are addressed. The results presented have been obtained using theoretical calculations and experimental techniques such as photoelectron spectroscopy (PES), low energy electron diffraction (LEED) and scanning tunneling microscopy (STM).

Si(001) surfaces with adsorbed alkali metals can function as prototype systems for studying properties of the technologically important family of metal-semiconductor interfaces. In this work, the effect of up to one monolayer (ML) of Li on the Si(001) surface is studied using a combination of experimental and theoretical techniques. Several models for the surface atomic structures have been suggested for 0.5 and 1 ML of Li in the literature. Through the combination of experiment and theory, critical differences in the surface electronic structures between the different atomic models are identified and used to determine the most likely model for a certain Li coverage.

In the literature, there are reports of an electronic structure at elevated temperature, that can be probed using angle resolved PES (ARPES), on the clean Ge(001) and Si(001) surfaces. The structure is quite unusual in the sense that it appears at an energy position above the Fermi level. Using results from a combined variable temperature ARPES and LEED study, the origin of this structure is determined. Various explanations for the structure that are available in the literature are discussed. It is found that all but thermal occupation of an ordinarily empty surface state band are inconsistent with our experimental data.

In a combined theoretical and experimental study, the surface core-level shifts on clean Si(001) and Ge(001) in the c(4×2) reconstruction are investigated. In the case of the Ge 3d core-level, no previous theoretical results from the c(4×2) reconstruction are available in the literature. The unique calculated Ge 3d surface core-level shifts facilitate the identification of the atomic origins of the components in the PES data. Positive assignments can be made for seven of the eight inequivalent groups of atoms in the four topmost layers in the Ge case. Furthermore, a similar, detailed, assignment of the atomic origins of the shifts on the Si surface is presented that goes beyond previously published results.

At a Sn coverage of slightly more than one ML, a 23 × 23 reconstruction can be obtained on the Si(111) surface. Two aspects of this surface are explored and presented in this work. First, theoretically derived results obtained from an atomic model in the literature are tested against new ARPES and STM data. It is concluded that the model needs to be revised in order to better explain the experimental observations. The second part is focused on the abrupt and reversible transition to a molten 1×1 phase at a temperature of about 463 K. ARPES and STM results obtained slightly below and slightly above the transition temperature reveal that the surface band structure, as well as the atomic structure, changes drastically at the transition. Six surface states are resolved on the surface at low temperature. Above the transition, the photoemission spectra are, on the other hand, dominated by a single strong surface state band. It shows a dispersion similar to that of a calculated surface band associated with the Sn-Si bond on a 1×1 surface with Sn positioned above the top layer Si atoms.

There has been extensive studies of the reconstructions on Si surfaces induced by adsorption of the group III metals Al, Ga and In. Recently, this has been expanded to Tl, i.e., the heaviest element in that group. Tl is different from the other elements in group III since it exhibits a peculiar behavior of the 6s2 electrons called the “inert pair effect”. This could lead to a valence state of either 1+ or 3+. In this work, core-level PES is utilized to find that, at coverages up to one ML, Tl exhibits a 1+ valence state on Si(111), in contrast to the 3+ valence state of the other group III metals. Accordingly, the surface band structure of the 1/3 ML 3 x √3 reconstruction is found to be different in the case of Tl, compared to the other group III metals. The observations of a 1+ valence state are consistent with ARPES results from the Si(001):Tl surface at one ML. There, six surface state bands are seen. Through comparisons with a calculated surface band structure, four of those can be identified. The two remaining bands are very similar to those observed on the clean Si(001) surface.

Place, publisher, year, edition, pages
Linköping: Linköping University Electronic Press, 2010. 39 p.
Linköping Studies in Science and Technology. Dissertations, ISSN 0345-7524 ; 1303
National Category
Natural Sciences
urn:nbn:se:liu:diva-54240 (URN)978-91-7393-433-6 (ISBN)
Public defence
2010-03-26, Planck, Fysikhuset, Campus Valla, Linköpings universitet, Linköping, 10:15 (English)
Available from: 2010-03-04 Created: 2010-03-04 Last updated: 2010-03-04Bibliographically approved

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