The study of the influence of different anode buffer layers on the performance of solar cells based on blends of polyfluorene copolymers, acting as electron donor, and [6,6]-phenyl-C61-butyric acid methylester (PCBM), acting as electron acceptor was presented. The construction of buffer later was done from different forms of poly(3, 4-ethylenedioxythiophene) poly-(styrenesulfonate) (PEDOT-PSS). Variations in open-circuit voltage, short-circuit current and fill factor were also observed. The anode buffer layer influences the photovoltage of polymer solar cells by controlling the conditions for charge injection at the anode.