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Frequency-dependent electrical conductivity of concentrated dispersions of spherical colloidal particles
Linköping University, The Institute of Technology. Linköping University, Department of Science and Technology.
Department of Chemical Engineering, Carnegie Mellon University, Pittsburgh, Pennsylvania, University of South Australia, Mawson Lakes, SA 5095, Australia.
2008 (English)In: Langmuir, ISSN 0743-7463, Vol. 24, no 9, 4512-4522 p.Article in journal (Refereed) Published
Abstract [en]

This paper outlines the application of a self-consistent cell-model theory of electrokinetics to the problem of determining the electrical conductivity of a dense suspension of spherical colloidal particles. Numerical solutions of the standard electrokinetic equations, subject to self-consistent boundary conditions, are implemented in formulas for the electrical conductivity appropriate to the particle-averaged cell model of the suspension. Results of calculations as a function of frequency, zeta potential, volume fraction, and electrolyte composition, are presented and discussed. © 2008 American Chemical Society.

Place, publisher, year, edition, pages
2008. Vol. 24, no 9, 4512-4522 p.
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Engineering and Technology
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URN: urn:nbn:se:liu:diva-46155DOI: 10.1021/la703777gOAI: oai:DiVA.org:liu-46155DiVA: diva2:267051
Available from: 2009-10-11 Created: 2009-10-11 Last updated: 2011-01-10

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Miklavcic, Stan

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