Electrochemical bandgaps of substituted polythiophenes
2003 (English)In: Journal of Materials Chemistry, ISSN 0959-9428, Vol. 13, no 6, 1316-1323 p.Article in journal (Refereed) Published
The electrochemical bandgaps for different soluble substituted polythiophenes have been measured by cyclic voltammetry. The effect of substituents on the oxidation/reduction potentials is discussed. Bandgaps obtained by cyclic voltammetry have been found to be in general higher than optical bandgaps. Among regioregular polymers substituted with a phenyl group at position 3 of the thiophene ring, examples are found that give very symmetric voltammograms. Rationalization for this behaviour is discussed from a conformational point of view.
Place, publisher, year, edition, pages
2003. Vol. 13, no 6, 1316-1323 p.
Engineering and Technology
IdentifiersURN: urn:nbn:se:liu:diva-46615DOI: 10.1039/b301403gOAI: oai:DiVA.org:liu-46615DiVA: diva2:267511