liu.seSearch for publications in DiVA
Change search
ReferencesLink to record
Permanent link

Direct link
The reaction of OH with H at elevated temperatures
Linköping University, Department of Physics, Chemistry and Biology. Linköping University, The Institute of Technology.
Studsvik Nuclear AB, SE-611 82 Nyköping, Sweden.
Riso National Laboratory, Roskilde, DK-4000, Denmark.
2002 (English)In: Radiation Physics and Chemistry, ISSN 0969-806X, Vol. 64, no 1, 29-33 p.Article in journal (Refereed) Published
Abstract [en]

The temperature dependence of the rate constant for the reaction between OH radicals and H atoms has been determined in Ar-saturated solutions at pH 2. The reaction was studied in the temperature range 5-233°C. The rate constants at 20°C and 200°C are 9.3×109 and 3.3×1010dm3mol-1s-1, respectively. The activation energy was found to be 8.2±0.4kJmol-1 (2.0±0.1kcalmol-1). This value is lower than that expected for a diffusion controlled reaction. © 2002 Elsevier Science Ltd. All rights reserved.

Place, publisher, year, edition, pages
2002. Vol. 64, no 1, 29-33 p.
Keyword [en]
Activation energy, H atom, OH radical, Pulse radiolysis, Rate constant
National Category
Natural Sciences
URN: urn:nbn:se:liu:diva-47058DOI: 10.1016/S0969-806X(01)00439-XOAI: diva2:267954
Available from: 2009-10-11 Created: 2009-10-11 Last updated: 2012-01-07

Open Access in DiVA

No full text

Other links

Publisher's full text
By organisation
Department of Physics, Chemistry and BiologyThe Institute of Technology
In the same journal
Radiation Physics and Chemistry
Natural Sciences

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 16 hits
ReferencesLink to record
Permanent link

Direct link