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High intercalation levels in lithium perylene stoichiometric compounds
Linköping University, The Institute of Technology. Linköping University, Department of Physics, Chemistry and Biology, Surface Physics and Chemistry .
Linköping University, The Institute of Technology. Linköping University, Department of Science and Technology.ORCID iD: 0000-0001-8845-6296
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2002 (English)In: Chemical Physics Letters, ISSN 0009-2614, E-ISSN 1873-4448, Vol. 354, no 5-6, 389-394 p.Article in journal (Refereed) Published
Abstract [en]

Both amorphous and polycrystalline films of the aromatic hydrocarbon perylene are found to accept as high as one lithium per 3.3±0.1 carbon atoms. Phases composed of stoichiometric compounds with two, four and six lithium atoms per molecule are observed. The intercalation involves a substantial charge transfer from the lithium atoms to the molecules. Moreover, a high binding energy of the dopant-induced valence band electronic states is observed by photoelectron spectroscopy. Those observations suggest a high energy storage capacity for small- and medium-size aromatic hydrocarbons and their potential use in batteries. © 2002 Elsevier Science B.V. All rights reserved.

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2002. Vol. 354, no 5-6, 389-394 p.
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Engineering and Technology
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URN: urn:nbn:se:liu:diva-47062DOI: 10.1016/S0009-2614(02)00148-3OAI: oai:DiVA.org:liu-47062DiVA: diva2:267958
Available from: 2009-10-11 Created: 2009-10-11 Last updated: 2017-12-13

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Friedlein, RainerCrispin, XavierStafström, SvenSalaneck, William R

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