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Efficient routes to glucosamine-myo-inositol derivatives, key building blocks in the synthesis of glycosylphosphatidylinositol anchor substances
Linköping University, The Institute of Technology. Linköping University, Department of Physics, Chemistry and Biology.
Öhberg, L., Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden.
Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden.
Linköping University, The Institute of Technology. Linköping University, Department of Physics, Chemistry and Biology, Organic Chemistry .
2002 (English)In: Tetrahedron, ISSN 0040-4020, E-ISSN 1464-5416, Vol. 58, no 7, 1387-1398 p.Article in journal (Refereed) Published
Abstract [en]

Short synthetic routes to protected derivatives of 2-amino-2-deoxy-a-D-glucopyranosyl-(1?6)-D-myo-inositol are described. Various 2-azido-2-deoxy-glucosyl donors were synthesized, starting from D-glucal or glucosamine hydrochloride. Derivatives of 1,2- and 2,3- D-myo-inositol-camphanylidene acetals were prepared to function as glycosyl acceptors. The subsequent glycosylations produced useful building blocks for the synthesis of GPI-anchor substances. © 2002 Elsevier Science Ltd. All rights reserved.

Place, publisher, year, edition, pages
2002. Vol. 58, no 7, 1387-1398 p.
Keyword [en]
Anchoring system, Glucosamine-myo-inositol, Glycosylphosphatidylinositol
National Category
Engineering and Technology
Identifiers
URN: urn:nbn:se:liu:diva-47105DOI: 10.1016/S0040-4020(01)01241-8OAI: oai:DiVA.org:liu-47105DiVA: diva2:268001
Available from: 2009-10-11 Created: 2009-10-11 Last updated: 2017-12-13

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Lindberg, JanKonradsson, Peter

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