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Pulsed EPR study of the (NO)2-Na+ triplet state adsorption complex
Boreskov Institute of Catalysis, 630090 Novosibirsk, Russian Federation.
Linköping University, The Institute of Technology. Linköping University, Department of Physics, Chemistry and Biology, Chemical Physics .
2001 (English)In: Chemical Physics Letters, ISSN 0009-2614, Vol. 349, no 5-6, 511-516 p.Article in journal (Refereed) Published
Abstract [en]

The (NO)2-Na+ triplet state complex stabilised in Na-A zeolites at low temperature was studied by pulsed EPR. The 3-pulse ESEEM spectra at 5 K were analysed by simulations in the time-domain, followed by Fourier transformation. The ESEEM was attributed to the interaction with Na+. The hyperfine coupling A(23Na)=(4.6, 4.6, 8.2) MHz and nuclear quadrupole Q(23Na)=(0.3, 0,3, -0.6) MHz tensors are of comparable magnitude as in the NO-Na+ complex determined earlier. The complexes are proposed to be either pairs of NO-Na+ or ON-Na+-NO.

Place, publisher, year, edition, pages
2001. Vol. 349, no 5-6, 511-516 p.
National Category
Engineering and Technology
URN: urn:nbn:se:liu:diva-47171DOI: 10.1016/S0009-2614(01)01250-7OAI: diva2:268067
Available from: 2009-10-11 Created: 2009-10-11 Last updated: 2011-01-13

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