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Conformational disorder of a substituted polythiophene in solution revealed by excitation transfer
Department of Chemical Physics, Lund University, PO Box 124, S-221 00, Lund, Sweden.
Department of Chemical Physics, Lund University, PO Box 124, S-221 00, Lund, Sweden.
Department of Chemical Physics, Lund University, PO Box 124, S-221 00, Lund, Sweden.
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2001 (English)In: Chemical Physics Letters, ISSN 0009-2614, E-ISSN 1873-4448, Vol. 339, no 1-2, 96-102 p.Article in journal (Refereed) Published
Abstract [en]

Anisotropy and isotropic transient absorption decays of a polythiophene derivative in dilute solution have been measured and compared to calculated decays on Monte Carlo simulated polymer chains to obtain knowledge about the geometrical conformation of the polymer. The polymer chain conformations are generated by a partially correlated self-avoiding random walk. Excitation migration along the isolated chain is modeled assuming a hopping mechanism. This approach can be used to determine conformational disorder and possible realizations of the polymer chains in solution as well as the trapping time and migration length of the excitation. © 2001 Elsevier Science B.V.

Place, publisher, year, edition, pages
2001. Vol. 339, no 1-2, 96-102 p.
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Engineering and Technology
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URN: urn:nbn:se:liu:diva-47391DOI: 10.1016/S0009-2614(01)00305-0OAI: oai:DiVA.org:liu-47391DiVA: diva2:268287
Available from: 2009-10-11 Created: 2009-10-11 Last updated: 2017-12-13

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Inganäs, Olle

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