liu.seSearch for publications in DiVA
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Electronic structure of some conjugated polymers for electron transport
Lögdlund, M., ACREO AB, Bredgatan 34, S-602 21 Norrköping, Sweden.
Show others and affiliations
2001 (English)In: Synthetic metals, ISSN 0379-6779, E-ISSN 1879-3290, Vol. 122, no 1, 67-72 p.Article in journal (Refereed) Published
Abstract [en]

The chemical and electronic structure of three different, strictly alternating copolymers, poly(2,5-diheptyl-1,4-phenylene-alt-1,4-naphthylene) (P14NHP), poly(2,5-diheptyl-1,4-phenylene-alt-2,6-naphthylene) (P26NHP) and poly(2,5-diheptyl-1,4-phenylene-alt-9,10-anthrylene) (P910AHP), have been studied by photoelectron spectroscopy and optical absorption spectroscopy. The experimental results have been analyzed using the results of quantum chemical calculations. In the geometrical structure of all three of the polymers there are large torsion angles between the phenylene unit and the naphthylene or anthrylene units. These large torsion angles lead to localization of the p-electron wave functions, and minimal conjugation along the polymer backbone. For all three polymers, the highest occupied molecular orbital is completely localized to the naphthylene or anthrylene unit. The frontier molecular orbital wave functions are very reminiscent of the highest occupied orbitals of the isolated naphthalene or anthracene molecules. The optical absorption spectra of all three polymers verify the existence of large optical band gaps, consistent with the large torsion angels. The first several optical transitions in the polymers are also very reminiscent of the transitions in single naphthalene and anthracene molecules.

Place, publisher, year, edition, pages
2001. Vol. 122, no 1, 67-72 p.
National Category
Engineering and Technology
Identifiers
URN: urn:nbn:se:liu:diva-47395DOI: 10.1016/S0379-6779(00)01365-5OAI: oai:DiVA.org:liu-47395DiVA: diva2:268291
Available from: 2009-10-11 Created: 2009-10-11 Last updated: 2017-12-13

Open Access in DiVA

No full text

Other links

Publisher's full text

Authority records BETA

Salaneck, William R

Search in DiVA

By author/editor
Salaneck, William R
By organisation
The Institute of TechnologySurface Physics and Chemistry
In the same journal
Synthetic metals
Engineering and Technology

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 173 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf