liu.seSearch for publications in DiVA
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Photoinduced isomerization of alkyl radicals in low-temperature solids: Dependence of its efficiency on the position of the radical site
Division of Molecular Chemistry, Grad. Sch. Eng., Hokkaido Univ., K., Sapporo, Japan.
Division of Molecular Chemistry, Grad. Sch. Eng., Hokkaido Univ., K., Sapporo, Japan.
Division of Molecular Chemistry, Grad. Sch. Eng., Hokkaido Univ., K., Sapporo, Japan.
Linköping University, The Institute of Technology. Linköping University, Department of Physics, Chemistry and Biology, Chemical Physics .
2001 (English)In: Chemical Physics Letters, ISSN 0009-2614, E-ISSN 1873-4448, Vol. 335, no 5-6, 375-380 p.Article in journal (Refereed) Published
Abstract [en]

Photoinduced isomerization of secondary alkyl radicals to primary alkyl radicals in glassy solids was studied by ESR spectroscopy. The efficiencies for 2-, 3- and 4-heptyl radicals in 77 K perdeuterated methylcyclohexane decrease in this order. Molecular orbital calculations indicate that the isomerization occurs through a hydride ion transfer from the methyl groups to the radical site in the lowest Rydberg state of secondary alkyl radicals. The dependence of its efficiency on the position of the radical site can be explained by variation of the negative charge at the methyl groups with the position of the radical site. © 2001 Elsevier Science B.V.

Place, publisher, year, edition, pages
2001. Vol. 335, no 5-6, 375-380 p.
National Category
Engineering and Technology
Identifiers
URN: urn:nbn:se:liu:diva-47458DOI: 10.1016/S0009-2614(01)00053-7OAI: oai:DiVA.org:liu-47458DiVA: diva2:268354
Available from: 2009-10-11 Created: 2009-10-11 Last updated: 2017-12-13

Open Access in DiVA

No full text

Other links

Publisher's full text

Authority records BETA

Lund, Anders

Search in DiVA

By author/editor
Lund, Anders
By organisation
The Institute of TechnologyChemical Physics
In the same journal
Chemical Physics Letters
Engineering and Technology

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 35 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf