liu.seSearch for publications in DiVA
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Adducts of zinc and copper(II) morpholinedithiocarbamate complexes with morpholine of the composition [M(Mf)(MfDtC)(2)] and [M(Mf)(MfDtC)(2)]center dot Mf: Synthesis, thermal analysis, EPR, and CP/MAS C-13 NMR
Russian Acad Sci, Far E Div, Amur Sci Ctr, Amur Inst Integrated Res, Blagoveshchensk 675000, Russia Amur State Univ, Blagoveshchensk 675027, Russia Linkoping Univ, S-58183 Linkoping, Sweden Lulea Univ Technol, S-97187 Lulea, Sweden.
Russian Acad Sci, Far E Div, Amur Sci Ctr, Amur Inst Integrated Res, Blagoveshchensk 675000, Russia Amur State Univ, Blagoveshchensk 675027, Russia Linkoping Univ, S-58183 Linkoping, Sweden Lulea Univ Technol, S-97187 Lulea, Sweden.
Russian Acad Sci, Far E Div, Amur Sci Ctr, Amur Inst Integrated Res, Blagoveshchensk 675000, Russia Amur State Univ, Blagoveshchensk 675027, Russia Linkoping Univ, S-58183 Linkoping, Sweden Lulea Univ Technol, S-97187 Lulea, Sweden.
Russian Acad Sci, Far E Div, Amur Sci Ctr, Amur Inst Integrated Res, Blagoveshchensk 675000, Russia Amur State Univ, Blagoveshchensk 675027, Russia Linkoping Univ, S-58183 Linkoping, Sweden Lulea Univ Technol, S-97187 Lulea, Sweden.
Show others and affiliations
2003 (English)In: Russian Journal of Inorganic Chemistry, ISSN 0036-0236, E-ISSN 1531-8613, Vol. 48, no 3, 415-421 p.Article in journal (Refereed) Published
Abstract [en]

The zinc and copper(II) morpholineditiohcarbamate complexes [M-2(MfDtc)(4)] and their adducts with morpholine [M(Mf)(MfDtc)(2)], including the solvated forms [M(Mf)(MfDtc)(2)] . Mf (M = Zn, Cu-63, Cu-65), have been synthesized and characterized by thermal analysis, EPR, and CP/MAS C-13 NMR data. Upon thermal destruction, the initial complexes, their adducts, and solvated forms lose weight in one, two, and three steps, respectively. The ultimate products of the thermal destruction of these complexes are zinc and copper sulfides. The range of the thermal destruction of the "dithiocarbamate part" is progressively shifted to lower temperatures in going from the initial binuclear complexes to their adducts and solvated forms. EPR shows that the geometry of the [CuS4N] chromophore in the [Cu(Mf)(MfDtc)(2)] adduct is close to square-pyramidal, the unpaired electron being predominantly localized in the metal 3d(x2-y2) AO. The outer-sphere solvation of the adduct is accompanied by structural reorganization at the molecular level. This reorganization involves a distortion of the [CuS4] base of the square-pyramidal polyhedron [CuS4N] toward a trigonal bipyramid. C-13 NMR shows that all of the zinc complexes under consideration are characterized by intramolecular nonequivalence of dithiocarbamate ligands. The N-15 NMR spectra adequately reflect the difference in the structural functions of pairs of dithiocarbamate ligands in [Zn-2(MfDtc)(4)].

Place, publisher, year, edition, pages
2003. Vol. 48, no 3, 415-421 p.
National Category
Engineering and Technology
Identifiers
URN: urn:nbn:se:liu:diva-48658OAI: oai:DiVA.org:liu-48658DiVA: diva2:269554
Available from: 2009-10-11 Created: 2009-10-11 Last updated: 2017-12-12

Open Access in DiVA

No full text

Authority records BETA

Lund, Anders

Search in DiVA

By author/editor
Lund, Anders
By organisation
The Institute of TechnologyChemical Physics
In the same journal
Russian Journal of Inorganic Chemistry
Engineering and Technology

Search outside of DiVA

GoogleGoogle Scholar

urn-nbn

Altmetric score

urn-nbn
Total: 50 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf