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Improved thermal stability of pyroelectric polymers by crosslinking of ferroelectric liquid crystals
Department of Polymer Technology, Royal Institute of Technology, Stockholm, Sweden.
Physics Department, Chalmers University of Technology, Göteborg, Sweden.
Department of Polymer Technology, Royal Institute of Technology, Stockholm, Sweden.
Department of Polymer Technology, Royal Institute of Technology, Stockholm, Sweden.
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2001 (English)In: Journal of Physical Chemistry B, ISSN 1520-6106, E-ISSN 1520-5207, Vol. 105, no 42, 10223-10227 p.Article in journal (Refereed) Published
Abstract [en]

Monofunctional ferroelectric liquid crystalline monomers and a blend of monofunctional/bifunctional ferroelectric liquid crystalline monomers were photopolymerized, yielding a side-chain liquid crystalline polymer and a cross-linked polymer, respectively. The cross-linked polymer exhibited higher thermal stability than the side-chain liquid crystalline polymer and was pyroelectric up to 170 °C, whereas the side-chain liquid crystalline polymer lost most of its pyroelectricity at 38 °C. It is shown by electrooptic and birefringence measurements that cross-linking in the unwound SmC* phase prevented the reoccurrence of the helical superstructure.

Place, publisher, year, edition, pages
2001. Vol. 105, no 42, 10223-10227 p.
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Natural Sciences
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URN: urn:nbn:se:liu:diva-49084DOI: 10.1021/jp0108972OAI: oai:DiVA.org:liu-49084DiVA: diva2:269980
Available from: 2009-10-11 Created: 2009-10-11 Last updated: 2017-12-12

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Eriksson, AndersLindgren, Mikael

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