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Surface properties of alumnas as studied by the electron-nuclear double resonance method
Russian Acad Sci, Siberian Div, Inst Chem Kinet & Combust, Novosibirsk, Russia Russian Acad Sci, Inst Catalysis, Siberian Div, Novosibirsk 630090, Russia Linkoping Univ, Dept Phys & Measurement Technol, S-58183 Linkoping, Sweden.
Russian Acad Sci, Siberian Div, Inst Chem Kinet & Combust, Novosibirsk, Russia Russian Acad Sci, Inst Catalysis, Siberian Div, Novosibirsk 630090, Russia Linkoping Univ, Dept Phys & Measurement Technol, S-58183 Linkoping, Sweden.
Linköping University, The Institute of Technology. Linköping University, Department of Physics, Chemistry and Biology, Chemical Physics .
Russian Acad Sci, Siberian Div, Inst Chem Kinet & Combust, Novosibirsk, Russia Russian Acad Sci, Inst Catalysis, Siberian Div, Novosibirsk 630090, Russia Linkoping Univ, Dept Phys & Measurement Technol, S-58183 Linkoping, Sweden.
2001 (English)In: Russian Journal of Physical Chemistry, ISSN 0036-0244, E-ISSN 1531-863X, Vol. 75, no 4, 629-635 p.Article in journal (Refereed) Published
Abstract [en]

XRD analysis, electron paramagnetic resonance (EPR), and electron-nuclear double resonance (ENDR) in conjunction with molecular anthraquinone probe, were: used to study the properties of various alumnas. It was demonstrated that the use of the ENDR method for analyzing the hyperfine coupling of the unpaired electron with the aluminum and hydrogen nuclei of the paramagnetic species arising at the surface upon anthraquinone adsorption makes it possible to determine the structure of surface complexes even when EPR spectra are insufficiently resolved. It was established that various complexes are formed at the surface of the alumnas due to changes in the positions of acceptor surface sites participating in the reaction.

Place, publisher, year, edition, pages
2001. Vol. 75, no 4, 629-635 p.
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Engineering and Technology
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URN: urn:nbn:se:liu:diva-49300OAI: oai:DiVA.org:liu-49300DiVA: diva2:270196
Available from: 2009-10-11 Created: 2009-10-11 Last updated: 2017-12-12

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Lund, Anders

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