liu.seSearch for publications in DiVA
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Vibronic coupling in the ground and excited states of oligoacene cations
Sánchez-Carrera, R.S., School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332-0400.
School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332-0400.
Da Silva Filho, D.A., School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332-0400.
Linköping University, The Institute of Technology. Linköping University, Department of Physics, Chemistry and Biology, Surface Physics and Chemistry .
Show others and affiliations
2006 (English)In: Journal of Physical Chemistry B, ISSN 1520-6106, E-ISSN 1520-5207, Vol. 110, no 38, 18904-18911 p.Article in journal (Refereed) Published
Abstract [en]

The vibrational coupling in the ground and excited states of positively charged naphthalene, anthracene, tetracene, and pentacene molecules is studied on the basis of a joint experimental and theoretical study of ionization spectra using high-resolution gas-phase photoelectron spectroscopy and first-principles correlated quantum-mechanical calculations. Our theoretical and experimental results reveal that, while the main contribution to relaxation energy in the ground state of oligoacene systems comes from high-energy vibrations, the excited-state relaxation energies show a significant redistribution toward lower-frequency vibrations. A direct correlation is found between the nature of the vibronic interaction and the pattern of the electronic state structure. © 2006 American Chemical Society.

Place, publisher, year, edition, pages
2006. Vol. 110, no 38, 18904-18911 p.
National Category
Engineering and Technology
Identifiers
URN: urn:nbn:se:liu:diva-50124DOI: 10.1021/jp057462pOAI: oai:DiVA.org:liu-50124DiVA: diva2:271020
Available from: 2009-10-11 Created: 2009-10-11 Last updated: 2017-12-12

Open Access in DiVA

No full text

Other links

Publisher's full text

Authority records BETA

Friedlein, RainerOsikowicz, WojciechSalaneck, William R

Search in DiVA

By author/editor
Friedlein, RainerOsikowicz, WojciechSalaneck, William R
By organisation
The Institute of TechnologySurface Physics and Chemistry
In the same journal
Journal of Physical Chemistry B
Engineering and Technology

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 226 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf