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Effects from hydrogen bonds on water structure in (H3O)2[Mo6Cl8X6yH2O X=Cl (y=7), Br (y=6), or I (y=6)
Department of Inorganic, Structural and Physical Chemistry, Arrhenius Laboratory, Stockholm University, S-10691, Stockholm, Sweden.
Department of Inorganic, Structural and Physical Chemistry, Arrhenius Laboratory, Stockholm University, S-10691, Stockholm, Sweden.
Department of Inorganic, Structural and Physical Chemistry, Arrhenius Laboratory, Stockholm University, S-10691, Stockholm, Sweden.
Department of Inorganic, Structural and Physical Chemistry, Arrhenius Laboratory, Stockholm University, S-10691, Stockholm, Sweden.
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2002 (English)In: Solid State Sciences, ISSN 1293-2558, Vol. 4, no 8, 1017-1022 p.Article in journal (Refereed) Published
Abstract [en]

The compounds (a) (H3O)2[Mo6Cl8Cl6]·7H2O, (b) (H3O)2[Mo6Cl8Br6]·6H2O and (c) (H3O)2[Mo6Cl8I6]·6H2O were synthesized from MoCl2 and the corresponding halide acid. The structures were determined by X-ray diffraction and refined in the monoclinic space groups, (a) C2/c and for (b) and (c) P21/a. The cell parameters were for (a), a=17.3607(2), b=9.1351(7), c=18.6300(2) Å and β=98.13(1)°, (b) a=17.4295(2), b=9.3803(10), c=9.3769(12) Å and β=101.04(1)° and (c) a=18.0083(10), b=9.7612(10), c=9.8139(12) Å and β=100.20(2)°. The positions of the hydrogen atoms were determined by theoretical energy optimization. The structures are compared with respect to the effect of hydrogen bonding on the water structure.

Place, publisher, year, edition, pages
2002. Vol. 4, no 8, 1017-1022 p.
Keyword [en]
hydrogen bonding, crystal structure
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:liu:diva-50645DOI: 10.1016/S1293-2558(02)01352-3OAI: oai:DiVA.org:liu-50645DiVA: diva2:271822
Available from: 2009-10-13 Created: 2009-10-13 Last updated: 2015-03-09

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Publisher's full texthttp://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6W6W-460J3GX-1&_user=650414&_coverDate=08%2F31%2F2002&_rdoc=3&_fmt=high&_orig=browse&_srch=doc-info(%23toc%236609%232002%23999959991%23332243%23FLA%23display%23Volume)&_cdi=6609&_sort=d&_docanchor=&_ct=16&_acct=C000034998&_version=1&_urlVersion=0&_userid=650414&md5=b916fe7e28a46fde34b21d3779c621e2

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Ojamäe, L.

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