liu.seSearch for publications in DiVA
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Valence excitations observed in resonant soft X-ray emission spectra of K2Ni(CN)4.H2O at the Ni 2p edge
Graduate University for Advanced Studies, Okazaki.
Graduate University for Advanced Studies, Okazaki.
Graduate University for Advanced Studies, Okazaki.
Uppsala University.
Show others and affiliations
2001 (English)In: Journal of Electron Spectroscopy and Related Phenomena, ISSN 0368-2048, E-ISSN 1873-2526, Vol. 114-116, 909-913 p.Article in journal (Refereed) Published
Abstract [en]

Resonant soft X-ray emission spectra have been measured at the Ni 2p edge of a planar nickel complex K2Ni(CN)4·H2O and interpreted by performing ab initio configuration interaction calculations. This cyano complex shows characteristic metal-to-ligand charge transfer (MLCT) bands in the Ni 2p photoabsorption spectra. Resonant soft X-ray emission via the MLCT intermediate states can be interpreted as valence MLCT excitations within a one-electron picture. On the other hand, resonant soft X-ray emission via the intra-atomic Ni 2p–3d intermediate state corresponding to the white line excitation shows significant electron correlation effects.

Place, publisher, year, edition, pages
2001. Vol. 114-116, 909-913 p.
Keyword [en]
Resonant soft X-ray emission; Molecular Ni complex; Metal-to-ligand charge transfer; Ni 2p photoabsorption
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:liu:diva-54980DOI: 10.1016/S0368-2048(00)00309-1OAI: oai:DiVA.org:liu-54980DiVA: diva2:312894
Available from: 2010-04-26 Created: 2010-04-26 Last updated: 2017-12-12Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full text

Authority records BETA

Magnuson, Martin

Search in DiVA

By author/editor
Magnuson, Martin
In the same journal
Journal of Electron Spectroscopy and Related Phenomena
Natural Sciences

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 175 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • oxford
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf