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Thermally enhanced mechanical properties of arc evaporated Ti0.34Al0.66N/TiN multilayer coatings
Linköping University, Department of Physics, Chemistry and Biology, Nanostructured Materials. Linköping University, The Institute of Technology.
Linköping University, Department of Physics, Chemistry and Biology, Nanostructured Materials. Linköping University, The Institute of Technology. (Nanostrukturerade material, Nanostructured Materials)
Seco Tools AB.
Linköping University, Department of Physics, Chemistry and Biology, Nanostructured Materials. Linköping University, The Institute of Technology.ORCID iD: 0000-0002-2286-5588
2010 (English)In: Journal of Applied Physics, ISSN 0021-8979, E-ISSN 1089-7550, Vol. 108, no 4, 044312- p.Article in journal (Refereed) Published
Abstract [en]

Cubic metastable Ti0.34Al0.66N/TiN multilayer coatings of three different periods, 25+50, 12+25, and 6+12 nm, and monoliths of Ti0.34Al0.66N and TiN where grown by reactive arc evaporation. Differential scanning calorimetry reveals that the isostructural spinodal decomposition to AlN and TiN in the multilayers starts at a lower temperature compared to the monolithic TiAlN, while the subsequent transformation from c-AlN to h-AlN is delayed to higher temperatures. Mechanical testing by nanoindentation reveals that, despite the 60 vol % TiN, the as-deposited multilayers show similar or slightly higher hardness than the monolithic Ti0.34Al0.66N. In addition, the multilayers show a more pronounced age hardening compared to the monolith. The enhanced hardening phenomena and improved thermal stability of the multilayer coatings are discussed in terms of particle confinement and coherency stresses from the neighboring TiN-layers.

Place, publisher, year, edition, pages
American Institute of Physics , 2010. Vol. 108, no 4, 044312- p.
National Category
Engineering and Technology
Identifiers
URN: urn:nbn:se:liu:diva-60236DOI: 10.1063/1.3463422ISI: 000281857100116OAI: oai:DiVA.org:liu-60236DiVA: diva2:355859
Note

Original Publication: Axel Knutsson, M. P. Johansson, L Karlsson and Magnus Odén, Thermally enhanced mechanical properties of arc evaporated Ti0.34Al0.66N/TiN multilayer coatings, 2010, JOURNAL OF APPLIED PHYSICS, (108), 4, 044312. http://dx.doi.org/10.1063/1.3463422 Copyright: American Institute of Physics http://www.aip.org/

Available from: 2010-10-08 Created: 2010-10-08 Last updated: 2017-12-12
In thesis
1. Thermal stability and mechanical properties of TiAlN-based multilayer and monolithic coatings
Open this publication in new window or tab >>Thermal stability and mechanical properties of TiAlN-based multilayer and monolithic coatings
2012 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

This thesis explores the thermal stability, microstructure, mechanical properties and cutting performance of multilayer and monolithic cubic TiAlN hard coatings. The aim is to increase the understanding of how the coatings’ microstructure and properties are affected by a layered structure when exposed to high temperatures.

The coatings were deposited on cemented carbide substrates, using a full scale industrial reactive cathodic arc evaporation system at Seco Tools AB. The thermal stability was investigated by differential scanning calorimetry and the microstructure was characterized with analytical transmission electron microscopy, x-ray diffractometry and atom probe tomography. The mechanical properties and cutting performance were studied by nanoindentation and metal machining, respectively.

The decomposition of cubic TiAlN transpire in two steps, first by an isostructural decomposition to cubic AlN- and cubic TiN-rich domains, which is followed by a phase transformation of cubic AlN to hexagonal AlN. In this work I show that the isostructural decomposition occurs in two stages, namely: Spinodal decomposition (initial stage) and coarsening (latter stage). During the initial stage, the phase separation proceeds with a constant size of the AlN- and TiN-rich domains, with a measured wavelength of ~2.8 nm. The time needed for the initial stage depends on the temperature as well as the composition. Following the spinodal decomposition, the AlN- and TiN-rich domains coarsen. The coarsening process is kinetically limited by diffusion and is not dependent on the composition.

If the cubic TiAlN is grown as a multilayer coating, with TiN as the alternating layer type, the decomposition behavior will be different. The isostructural spinodal decomposition in the multilayers starts at a lower temperature compared to the monolithic TiAlN, while the subsequent transformation from cubic AlN to hexagonal AlN is delayed to higher temperatures. The TiN-layers confine the coarsening of the hexagonal AlN resulting in smaller domains. Mechanical testing reveals that, despite the 60 vol. % of the softer TiN, the asdeposited multilayers show a similar or slightly higher hardness than the monolithic Ti0.34Al0.66N. In addition, the multilayers show a more pronounced age hardening compared to the monoliths.

For short annealing times (<1 min) at 850 °C a layer rich in AlN followed by areas rich in TiN is observed parallel to the TiAlN/TiN interfaces in the multilayer stack. This microstructural feature indicates the presence of surface directed spinodal decomposition in the multilayer coatings. The lack of a layered structure further into the TiAlN-layer is due to the growth induced elemental fluctuations, which trigger an earlier onset of the coarsening. The coherency stresses generated across the multilayer interfaces also influence the decomposition. However, in this case the surface directed spinodal decomposition is the dominating mechanism for the altered thermal stability.

Finally, during metal machining of AISI-316L stainless steel the Ti0.34Al0.66N/TiN multilayers, regardless of period, show an improved crater wear resistance compared to a Ti0.34Al0.66N monolith. The multilayer  structure and the local coherency across the multilayer interfaces, seen in the as-deposited state, is present also after the metal machining. It is further revealed that the Ti0.34Al0.66N layer decomposes to AlN- and TiN-rich domains during the cutting operation.

Place, publisher, year, edition, pages
Linköping: Linköping University Electronic Press, 2012. 76 p.
Series
Linköping Studies in Science and Technology. Dissertations, ISSN 0345-7524 ; 1474
National Category
Natural Sciences
Identifiers
urn:nbn:se:liu:diva-84705 (URN)978-91-7519-801-9 (ISBN)
Public defence
2012-11-16, Planck, Fysikhuset, Campus Valla, Linköpings univeristet, Linköping, 10:15 (English)
Opponent
Supervisors
Available from: 2012-10-17 Created: 2012-10-17 Last updated: 2013-10-02Bibliographically approved

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