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POLYFERROCENES AS MEDIATORS IN AMPEROMETRIC BIOSENSORS FOR GLUCOSE
CRANFIELD INST TECHNOL,CRANFIELD BIOTECHNOL CTR,CRANFIELD MK43 0AL,BEDS,ENGLAND; UNIV WITWATERSRAND,DEPT CHEM,JOHANNESBURG 2001,SOUTH AFRICA; .
CRANFIELD INST TECHNOL,CRANFIELD BIOTECHNOL CTR,CRANFIELD MK43 0AL,BEDS,ENGLAND; UNIV WITWATERSRAND,DEPT CHEM,JOHANNESBURG 2001,SOUTH AFRICA; .
Cranfield University, UK.ORCID iD: 0000-0002-1815-9699
CRANFIELD INST TECHNOL,CRANFIELD BIOTECHNOL CTR,CRANFIELD MK43 0AL,BEDS,ENGLAND; UNIV WITWATERSRAND,DEPT CHEM,JOHANNESBURG 2001,SOUTH AFRICA; .
1993 (English)In: Analytica Chimica Acta, ISSN 0003-2670, E-ISSN 1873-4324, Vol. 281, no 3, 453-459 p.Article in journal (Refereed) Published
Abstract [en]

This paper describes the first successful application of polymeric ferrocenes as mediators in amperometric biosensors. The results have implications for the design of stable biosensors and bioelectronic devices involving electron transfer from oxidoreductases to electrode surfaces. The behaviour of two ferrocene polymers in enzyme electrodes was explored and a distinctive pH profile was noted. It is suggested that changes in either the enzyme conformation or the polymer in response to hydrogen ion concentration may explain the difference in behaviour between monomeric and polymeric ferrocenes.

Place, publisher, year, edition, pages
Elsevier Science B.V., Amsterdam. , 1993. Vol. 281, no 3, 453-459 p.
Keyword [en]
AMPEROMETRY; BIOSENSORS; ENZYMATIC METHODS; ENZYME ELECTRODES; FERROCENES; GLUCOSE; GLUCOSE OXIDASE
National Category
Engineering and Technology
Identifiers
URN: urn:nbn:se:liu:diva-65295ISI: A1993MA13200002OAI: oai:DiVA.org:liu-65295DiVA: diva2:394937
Available from: 2011-02-04 Created: 2011-02-04 Last updated: 2017-12-11

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TURNER, APF

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