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Novel regioregular poly(3-hexylthiophene)-based polycationic block copolymers
University Mons UMONS.
University Mons UMONS.
University Mons UMONS.
University Mons UMONS.
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2011 (English)In: POLYMER BULLETIN, ISSN 0170-0839, Vol. 66, no 1, 51-64 p.Article in journal (Refereed) Published
Abstract [en]

Regioregular poly(3-hexylthiophene) has been successfully incorporated into various poly(N,N-dimethylamino-2-ethyl methacrylate)-based block copolymers, i.e., P3HT-b-PDMAEMA, via Grignard metathesis (GRIM) method and atom transfer radical polymerization (ATRP) reactions. The structure of the diblock copolymers was fully confirmed by FT-IR, H-1 NMR spectroscopy, gel permeation chromatography (GPC), and ultraviolet-visible spectroscopy (UV-vis). The recovered copolymers could be treated by protonation of the pending tertiary amine functions and depending on the relative content in PDMAEMA, the copolymers could be solubilized in more polar solvents where P3HT alone proved to be totally insoluble.

Place, publisher, year, edition, pages
Springer Science Business Media , 2011. Vol. 66, no 1, 51-64 p.
Keyword [en]
Poly(3-hexylthiophene), Poly(N, N-dimethylamino-2-ethyl methacrylate), ATRP, Block copolymer
National Category
Engineering and Technology
URN: urn:nbn:se:liu:diva-65714DOI: 10.1007/s00289-010-0257-2ISI: 000286297800004OAI: diva2:398518
Available from: 2011-02-18 Created: 2011-02-18 Last updated: 2013-09-12

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Crispin, Xavier
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Department of Science and TechnologyThe Institute of Technology
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ReferencesLink to record
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