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The Effect of additive on performance and shelf-stability of HSX-1/PCBM photovoltaic devices
Linköping University, Department of Physics, Chemistry and Biology, Biomolecular and Organic Electronics. Linköping University, Faculty of Science & Engineering.
Linköping University, Department of Physics, Chemistry and Biology, Biomolecular and Organic Electronics. Linköping University, Faculty of Science & Engineering.
Linköping University, Department of Physics, Chemistry and Biology, Biomolecular and Organic Electronics. Linköping University, Faculty of Science & Engineering.
Linköping University, Department of Physics, Chemistry and Biology, Biomolecular and Organic Electronics. Linköping University, The Institute of Technology.
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2011 (English)In: Organic electronics, ISSN 1566-1199, Vol. 12, no 9, 1544-1551 p.Article in journal (Refereed) Published
Abstract [en]

How 1,8-diiodooctane (DIO) enhances performance of polymer solar cells based on polymer HXS-1 and fullerene [6,6]-phenyl C(71)-butyric acid methyl ester (PC(71)BM) from 3.6% to 5.4% is scrutinized with several techniques by comparing devices or blend films spin-coated from dichlorobenzene (DCB) to those from DCB/DIO (97.5:2.5 v/v). Morphology of blend films is examined with atomic force microscopy (AFM), transmission electron microscopy (TEM) and electron tomography (3-D TEM), respectively. Charge generation and recombination is studied with photoluminescence, and charge transport with field effect transistors. The morphology with domain size in 10-20 nm and vertical elongated clusters formed in DIO system is supposed to facilitate charge transport and minimize charge carrier recombination, which are the main reasons for enhancing power conversion efficiency (PCE) from 3.6% (without DIO) to 5.4% (with DIO). Furthermore, a two year inspection shows no significant impact of DIO on the shelf-stability of the solar cells. No visible degradation in the second year indicates that the morphology of the active layers in the devices is relatively stable after initial relaxation in the first year.

Place, publisher, year, edition, pages
Elsevier Science B.V., Amsterdam. , 2011. Vol. 12, no 9, 1544-1551 p.
Keyword [en]
Polymer solar cell; Additive; Morphology; Shelf-stability; Phase separation
National Category
Engineering and Technology
URN: urn:nbn:se:liu:diva-69770DOI: 10.1016/j.orgel.2011.05.028ISI: 000292685700013OAI: diva2:433619

Original Publication: Weiwei Li, Yi Zhou, Viktor Andersson, Mattias Andersson, Yi Thomann, Clemens Veit, Kristofer Tvingstedt, Ruiping Qin, Zhishan Bo, Olle Inganäs, Uli Wuerfel and Fengling Zhang, The Effect of additive on performance and shelf-stability of HSX-1/PCBM photovoltaic devices, 2011, Organic electronics, (12), 9, 1544-1551. Copyright: Elsevier Science B.V., Amsterdam.

Available from: 2011-08-10 Created: 2011-08-08 Last updated: 2015-05-29Bibliographically approved
In thesis
1. Electron tomography and optical modelling for organic solar cells
Open this publication in new window or tab >>Electron tomography and optical modelling for organic solar cells
2012 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

Organic solar cells using carbon based materials have the potential to deliver cheap solar electricity. The aim is to be able to produce solar cells with common printing techniques on flexible substrates, and as organic materials can be made soluble in various solvents, they are well adapted to such techniques. There is a large variation of organic materials produced for solar cells, both small molecules and polymers. Alterations of the molecular structure induce changes of the electrical and optical properties, such as band gap, mobility and light absorption. During the development of organic solar cells, the step of mixing of an electron donor and an electron acceptor caused a leap in power conversion efficiency improvement, due to an enhanced exciton dissociation rate. Top performing organic solar cells now exhibit a power conversion efficiency of over 10%. Currently, a mix of a conjugated polymer, or smaller molecule, and a fullerene derivative are commonly used as electron donor and acceptor. Here, the blend morphology plays an important role. Excitons formed in either of the donor or acceptor phase need to diffuse to the vicinity of the donor-acceptor interface to efficiently dissociate. Exciton diffusion lengths in organic materials are usually in the order of 5-10 nm, so the phases should not be much larger than this, for good exciton quenching. These charges must also be extracted, which implies that a network connected to the electrodes is needed. Consequently, a balance of these demands is important for the production of efficient organic solar cells.

Morphology has been found to have a significant impact on the solar cell behaviour and has thus been widely studied. The aim of this work has been to visualize the morphology of active layers of organic solar cells in three dimensions by the use of electron tomography. The technique has been applied to materials consisting of conjugated polymers blended with fullerene derivatives. Though the contrast in these blends is poor, three-dimensional reconstructions have been produced, showing the phase formation in three dimensions at the scale of a few nanometres. Several material systems have been investigated and preparation techniques compared.

Even if excitons are readily dissociated and paths for charge extraction exist, the low charge mobilities of many materials put a limit on film thickness. Although more light could be absorbed by increased film thickness, performance is hampered due to increased charge recombination. A large amount of light is thus reflected and not used for energy conversion. Much work has been put into increasing the light absorption without hampering the solar cell performance. Aside from improved material properties, various light trapping techniques have been studied. The aim is here to increase the optical path length in the active layer, and in this way improve the absorption without enhanced extinction coefficient.

At much larger dimensions, light trapping in solar cells with folded configuration has been studied by the use of optical modelling. An advantage of these V-cells is that two materials with complementing optical properties may be used together to form a tandem solar cell, which may be connected in either serial or parallel configuration, with maintained light trapping feature. In this work optical absorption in V-cells has been modelled and compared to that of planar ones.

Place, publisher, year, edition, pages
Linköping: Linköping University Electronic Press, 2012. 63 p.
Linköping Studies in Science and Technology. Dissertations, ISSN 0345-7524 ; 1414
Organic solar cells, Electron tomography, Optical modelling
National Category
Natural Sciences
urn:nbn:se:liu:diva-72903 (URN)978-91-7393-007-9 (ISBN)
Public defence
2012-02-03, Planck, Fysikhuset, Campus Valla, Linköpings universitet, Linköping, 10:15 (English)
Available from: 2011-12-13 Created: 2011-12-09 Last updated: 2012-01-03Bibliographically approved

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Zhou, YiAndersson, ViktorAndersson, MattiasTvingstedt, KristoferInganäs, OlleZhang, Fengling
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